Position wave function of energy eigenstates in 1D box

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SUMMARY

The discussion focuses on finding the position-space wave functions ψn(x) of energy eigenstates for a particle confined in a one-dimensional box of size L, where the potential V(x) is zero within the box and infinite outside. The Hamiltonian operator is defined as H = p²/2m + V(x). The correct form of the wave function is derived as ψn(x) = A sin(kx) + B sin(kx), with specific boundary conditions leading to quantized values of k. The solution must be normalized such that <ψn|ψn> = 1.

PREREQUISITES
  • Understanding of quantum mechanics, specifically the Schrödinger equation.
  • Familiarity with boundary conditions in quantum systems.
  • Knowledge of normalization of wave functions.
  • Concept of energy eigenstates in quantum mechanics.
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  • Study the derivation of energy eigenvalues for a particle in a 1D infinite potential well.
  • Learn about normalization techniques for wave functions in quantum mechanics.
  • Explore the implications of boundary conditions on wave functions.
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Students and professionals in physics, particularly those studying quantum mechanics, as well as educators teaching concepts related to wave functions and energy eigenstates in confined systems.

jasonchiang97
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Homework Statement


Consider a particle which is confined in a one-dimensional box of size L, so that the position space wave function ψ(x) has to vanish at x = 0 and x = L. The energy operator is H = p2/2m + V (x), where the potential is V (x) = 0 for 0 < x < L, and V (x) = ∞ otherwise.

Find the position-space wave functions ψn(x) ≡ <x|ψn> of the energy eigenstates |ψn>. Make sure that your wave functions are normalized, so that <ψnn> = 1

Homework Equations



maybe

<x'|x|ψ> = x'<x'|ψ>
1 =

The Attempt at a Solution



I'm not 100% sure what the question is asking for but I'm guessing it's asking me to find the RHS of

ψn(x) ≡ <x|ψn>

I can write the RHS as a sum since energy eigenstates are discrete

<x|ψn> = <x|1|ψn> = ∑ψni2

I'm not sure if this is the right step but it's all I could come up with.
 
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Are you familiar with the Schrödinger equation for such a system?
 
Chandra Prayaga said:
Are you familiar with the Schrödinger equation for such a system?

Yes, for a mass moving in 1D, the Schrödinger equation gives

n(x) + Vψn(x) = Eψn(x)

H = Hamiltonian

So if I solve the equation for a 1D box I would get something like

ψn(x) = Asin(kx)+Bsin(kx)

Do I then solve for k,A, and B?
 
I am unsure of what it means by position wave functions of energy eigenstates. Does it mean Solve for ψn(x) for the definite levels of energy levels?
 
Yes. You have the solution, now apply the boundary conditions and normalization. Only specific ##k## do the trick and they can be numbered from n=0 to infinity.

(I assumed you wrote A sin .. + B cos .. ?)
 

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