Q about current article: On-demand Hydrogen Generation : ACS Nano Letters

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The discussion centers around a research abstract that mentions a process for splitting water molecules without the use of light, heat, or electricity. A key question raised is the source of energy for this reaction. It is clarified that the reaction involving silicon (Si) and water (H2O) is exothermic, producing silicon dioxide (SiO2) and hydrogen gas (H2). This exothermic nature indicates that the reaction releases energy, which is sufficient for the water splitting process. The conversation also touches on the similarity of this method to using an aluminum/gallium alloy for water splitting, emphasizing that the initial assumption of a catalytic process was incorrect.
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Here is the abstract: http://pubs.acs.org/doi/abs/10.1021/nl304680w

I would need to pay the $35 so I have not read the full text.

Question: it says "...without Light, Heat, or Electricity." Where is the energy required to split the water molecules coming from?

Jeff
 
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2H2O +Si -> SiO2 +2H2

This reaction is very exothermic due to the high energy of formation of SiO2.
 
In a way it is not much different from using Al/Ga alloy for the same purpose.
 
Thank you both. I foolishly thought they might be claiming some kind of catalysis. I saw the error of my ways soon after posting.
 
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