I don't know what these numbers are that you are using.
There are generally 3 directions of shear stress in a member...vertically up and down along the cross section, horizontally left to right or right to left along the cross section, and longitudinally into and out of the plane of the cross section.
In the web, shear stresses are vertical and longitudinal. The stresses are determined by cutting horizontally at the point of interest, and using the Q value of the area above the cut, and then the longitudinal stresses act at the top and bottom of the cut face, into the plane. There are no horizontal shear stresses in the web , since if you were to make a vertical cut thru the entire web, the Q to the right of the cut would be zero, since the centroid of the area to the right of the cut is at the neutral axis, such that the vert distance from the centroid to the NA is 0.
In the flange, shear stresses are vertical, horizontal, and longitudinal. The horizontal stresses are determined by cutting vertically at the point of interest, and using the Q value of the area to the right of the cut, and then the longitudinal stresses act at the side of the cut face, into the plane. There are small average vertical shear stresses in the web , which are typically ignored except when designing welds for a cover plate over the flange. The assumed zero vertical shear stress in the web, and its associated longitudinal stress , designated as (q'), is shown in figure e of the 1st post. The horiz shear stress , q, is non-zero.