Solving Spinal Structure Mystery in Solid State Chemistry

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Discussion Overview

The discussion revolves around the concept of spinal structures in solid state chemistry, specifically focusing on the normal spinel structure and its lattice system. Participants seek clarification on terminology and the arrangement of cations and anions within this structure.

Discussion Character

  • Exploratory, Technical explanation, Conceptual clarification

Main Points Raised

  • One participant initially inquires about the definition of a "normal spinal structure," indicating confusion over the terminology used.
  • Another participant suggests that the term intended was "spinel" and provides links to external resources for further information on spinel structures.
  • A subsequent post confirms the correction of the term and discusses the occupancy of cation sites in the spinel structure, specifically mentioning the +2 cation in tetrahedral voids and the +3 cation in octahedral voids.
  • There is a repeated request for clarification regarding the original question about the lattice system of anions in a normal spinel structure.

Areas of Agreement / Disagreement

Participants appear to agree on the correction of the term from "spinal" to "spinel," but the discussion remains unresolved regarding the specific details of the lattice system and the original inquiry.

Contextual Notes

There are limitations in the clarity of the original question, and the discussion reflects uncertainty about the specific aspects of the spinel structure being addressed.

Kitrak
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In solid state chemistry, what's a normal spinal structure? I came across a question about it and I couldn't find any credible answers.
 
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Spinal?

Please elaborate, your question (even assuming I guess correctly what it is about) is rather cryptic.
 
TeethWhitener, you're right. The book printed it wrong I guess. So the +2 cation occupies 1/8th of the tetrahedral voids and the +3 cation occupies half of the octahedral voids?
 
Borek said:
Spinal?

Please elaborate, your question (even assuming I guess correctly what it is about) is rather cryptic.
*spinel
Sorry about the spelling mistake :P
The original question was about the lattice system of the anions in a normal spinel structure.
 

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