Vapor pressure of water (kinetics)

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The discussion revolves around the collection of hydrogen gas generated from a reaction between a metal and hydrochloric acid, with concerns about the presence of water vapor in the collected gas. The method involved using an inverted conical flask submerged in water to capture the hydrogen, but it raises questions about the accuracy of the gas volume measurement due to potential water vapor contamination. Participants discuss the possibility of reaching equilibrium between liquid water and water vapor over time, suggesting that keeping the setup longer may allow for accurate measurement of water vapor content. The use of a desiccant is proposed as a potential solution to eliminate water vapor from the gas mixture, although it is acknowledged that determining the exact contribution of water vapor to the total pressure can be challenging if the system is not in equilibrium.
feiyangflash
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Hi All,

I tried to collected hydrogen gas generated from the reaction between a metal and hydrochloric acid. I put a inverted conical flask in the water, and the generated H2 would push the water out of the flask, and then the H2 was collected. However, I guess there is water vapor mixed together with the H2, and therefore the gas volume I read is actually for the summation of H2 and water vapor, rather than the H2. I could find the equilibrium vapor pressure of water at room temperature. However, I don't know whether the equilibrium between liquid water and water vapor is reached or not. The whole reaction last for 1/2 hour.

Is there a way to figure out how much the pressure contributed by water vapor is?

Thank you!

Fei
 
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could you simply use a desiccant to get rid of the water vapor?

if, as you suggest, that there may be a non-equilibrium amount of water vapor in your system, it would be difficult to attach a numerical value to how much is present.
 
Thank you for the reply!

I keep it for much longer time, so the equilibrium between the water vapor and liquid water is reached, and then I know how much water vapor there is in the mixed gas of hydrogen and water vapor.


uby said:
could you simply use a desiccant to get rid of the water vapor?

if, as you suggest, that there may be a non-equilibrium amount of water vapor in your system, it would be difficult to attach a numerical value to how much is present.
 
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