Volume integral over a gradient (quantum mechanics)

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SUMMARY

The discussion focuses on solving three problems related to quantum mechanics, specifically involving integrals and density of states. The first problem, calculating the density of states for a free particle in a three-dimensional box of linear size L, yields the result $$\frac{m^{3/2}L^3 \sqrt{E}}{\pi^2 \hbar^2 \sqrt{2}}$$ using methods from Sakurai. The second problem demonstrates the identity ##\int f \nabla g \, d^3 x=-\int g \nabla f \, d^3 x## under the condition that ##\lim_{r \rightarrow \infty} [f(x)g(x)]=0##, which is proven using the divergence theorem. The third problem involves calculating the integral ##\int xe^{-i\mathbf{q \cdot x}} e^{-Zr/a_0} \, d^3 x##, which is noted to be complex and requires further exploration of the relationships between the functions involved.

PREREQUISITES
  • Understanding of quantum mechanics principles, particularly in three-dimensional systems.
  • Familiarity with vector calculus, including divergence and gradient operations.
  • Knowledge of integral calculus in multiple dimensions.
  • Experience with the divergence theorem and its applications in physics.
NEXT STEPS
  • Study the derivation of density of states in quantum mechanics, focusing on three-dimensional systems.
  • Learn about the divergence theorem and its implications in vector calculus.
  • Explore advanced techniques for evaluating integrals involving exponential functions in quantum mechanics.
  • Investigate the properties of scalar and vector fields in the context of quantum mechanics.
USEFUL FOR

This discussion is beneficial for physics students, particularly those studying quantum mechanics, as well as researchers and educators looking to deepen their understanding of integrals and vector calculus in physical contexts.

astrocytosis
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Homework Statement



1) Calculate the density of states for a free particle in a three dimensional box of linear size L.

2) Show that ##\int f \nabla g \, d^3 x=-\int g \nabla f \, d^3 x## provided that ##lim_{r \rightarrow \inf} [f(x)g(x)]=0##

3) Calculate the integral ##\int xe^{-i\mathbf{q \cdot x}} e^{-Zr/a_0} \, d^3 x##

Homework Equations



Not sure

The Attempt at a Solution


[/B]
(1) seems straightforward; I followed the method in Sakurai and got $$\frac{m^{3/2}L^3 \sqrt{E}}{\pi^2 \hbar^2 \sqrt{2}}. $$ (2) and (3) though I'm confused about the context. am I supposed to be thinking of some specific functions when it comes to f and g? the limit is in r but the functions are of x? am I missing some identities that would help me solve it?

(3) doesn't look difficult but the professor said the calculation would be quite involved, so I'm clearly not thinking about it correctly, and I'm not seeing how the result (2) would help...
 
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OK, I think all I need for (2) is the product rule since f*g is going to zero, but I'm still not sure how this relates to (3)
 
Hi astrocytosis,

I didn't check (1) so I can't really comment on that.

(2) To see this consider the follwoing. Let ##\bf v## be a vector field and ##u## a scalar field. Now one can prove that the following identity holds
$$
\mathop{\rm div}({\bf v}u)=
(\mathop{\rm div}{\bf v})\,u+
{\bf v}\cdot\mathop{\rm grad}u.
$$
Now let ##G## be a finite domain. We than have
$$
\int_{\partial G}{\bf v}\,u\;{\rm d}\boldsymbol\sigma
=\int_G\mathop{\rm div}({\bf v}u)\;{\rm d}^3y
=\int_G(\mathop{\rm div}{\bf v})\,u\;{\rm d}^3y+
\int_G{\bf v}\cdot\mathop{\rm grad}u\;{\rm d}^3y
$$
Now if we let ##G\longrightarrow \mathbb{R}^3## and the limit you were given holds the integral over ##\partial G## vanishes and you get the desired identity.
 

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