Why does atom's attraction to electron increase in periods ?

In summary, the attraction of the nucleus to the outermost electron increases across a period due to the increase in positive charge from adding protons. However, this does not decrease with the addition of more electrons as the force is not divided between them. This concept is not accurately explained in the AS chemistry book quoted. The decrease in ionic radius of a positive ion compared to its corresponding neutral atom is due to the decrease in repulsive forces between the remaining electrons, allowing them to settle closer to the nucleus.
  • #1
KingCrimson
43
1
Why does the nucleus' attraction to the outermost electron increase across a period?
I have been told that this is because each time you go across a period one step to the right, you add one proton and so there is more positive charge, but isn't it true that you also add one electron ? and so the positive charge even though it has increased is divided between more electrons and so the attraction of electrons by the nucleus stays the same ?
This could only mean that the positive charge's attraction to each electron is not divided, but this defies what my a level book says.
thanks in advance
 
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  • #2
You're correct, it is not divided.

The electrostatic force a single charge like an electron "feels" from the nucleus increases with the number of protons, and it doesn't decrease as you add more electrons in the same way as the force of Earth's gravity on a single person doesn't decrease as you add more people.

KingCrimson said:
but this defies what my a level book says.
There's probably some misunderstanding there. Can you quote what your book says?
 
  • #3
Page 75 Edexcel AS chemistry bob fullick and ann mcduel
"A positive ion always has a smaller ionic radius than the original atom, This is because the loss of electron/s means that the remaining electrons each have a greater (share) of the positive charge of the nucleus so are more tightly bound"
they say Share as if the force is divided between electrons.
 
  • #4
This looks like a blunder to me, but you better wait for other members to voice their opinions.
 
  • #5
Are you discussing atoms, ions, ionization potential, or electron affinity?
 
  • #6
KingCrimson said:
Page 75 Edexcel AS chemistry bob fullick and ann mcduel
"A positive ion always has a smaller ionic radius than the original atom, This is because the loss of electron/s means that the remaining electrons each have a greater (share) of the positive charge of the nucleus so are more tightly bound"
they say Share as if the force is divided between electrons.

That's a completely awful wrong terrible somewhat misleading explanation, but it is true that (all else being the same) a positive ion has a smaller diameter than the corresponding neutral atom. The force between the electrons is repulsive, so tends to force the electrons away from one another and outwards. When we remove one electron this force becomes smaller while the attraction to the nucleus remains the same, so the remaining electrons can settle in a bit closer.
 
  • #7
Nugatory said:
That's a completely awful wrong terrible somewhat misleading explanation, but it is true that (all else being the same) a positive ion has a smaller diameter than the corresponding neutral atom. The force between the electrons is repulsive, so tends to force the electrons away from one another and outwards. When we remove one electron this force becomes smaller while the attraction to the nucleus remains the same, so the remaining electrons can settle in a bit closer.
That's a much better way of putting it. It's due to the net charge (i.e. a difference) and not the "sharing" which is a ratio effect.
 

1. Why does an atom's attraction to electron increase in periods?

As an atom's atomic number increases across a period, the number of protons in the nucleus also increases. This leads to a stronger positive charge in the nucleus, which in turn increases the attraction between the positively charged nucleus and the negatively charged electrons. This results in a stronger overall attraction between the atom and its electrons.

2. How does an atom's electron configuration affect its attraction to electrons in periods?

An atom's electron configuration determines the number of energy levels and sublevels in which its electrons reside. As the atomic number increases across a period, the number of electrons also increases, causing the outermost energy level to fill up and become more stable. This results in a stronger attraction between the nucleus and the outermost electrons, making it more difficult for additional electrons to be added.

3. Does an atom's size affect its attraction to electrons in periods?

Yes, an atom's size does affect its attraction to electrons in periods. As the atomic number increases, the number of protons and electrons also increases, resulting in a larger overall size of the atom. This increase in size results in a weaker attraction between the nucleus and the outermost electrons, making it easier for additional electrons to be added.

4. How does the periodic trend of electronegativity relate to an atom's attraction to electrons in periods?

Electronegativity is a measure of an atom's ability to attract electrons towards itself in a chemical bond. As the atomic number increases across a period, the electronegativity also increases. This is due to the stronger attraction between the nucleus and the outermost electrons, making it more difficult for other atoms to take away those electrons.

5. Are there any exceptions to the trend of increasing attraction to electrons in periods?

Yes, there are a few exceptions to this trend. The elements in group 18, also known as the noble gases, have a full outermost energy level and are therefore very stable. They do not have a strong attraction to electrons and are therefore less likely to form chemical bonds. Additionally, there are some anomalies in the transition metal elements due to their unique electron configurations.

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