Why does total internal reflection happen in glass?

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Total internal reflection in glass occurs when light travels from a denser medium to a less dense medium at an angle greater than the critical angle. This phenomenon is determined by the refractive indices of the two media involved. Maxwell's equations explain that specific conditions allow light to be completely reflected rather than refracted. Additionally, at Brewster's angle, one polarization of light is entirely refracted while the other is reflected, which is why polarizing sunglasses are effective for reducing glare. Understanding these principles is essential for applications in optics and photonics.
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Why does total internal reflection happen in glass?
 
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What determines whether total internal reflection can occur?
 
any microscopic answer?
 
If you go back to Maxwell's equations for the propagation of electromagnetic radiation (E cross H) in media and at surfaces, you will find that there are certain cases where light will be entirely internally reflected. Also, you will find from Maxwell's equations that at a specific angle of incidence on water or glass, one polarization is entirely refracted, and the other completely reflected (Brewster's angle). (Why do fishermen wear polarizing sunglasses?)
 

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