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The 2nd law of thermodynamics says that the entropy of the universe can (probabilistically) never decrease. It does not say that any particular physical system will prefer chaos to equilibrium, and it does not say that particles are going to ignore the basic laws of mechanics. Unless you are going to calculate the entropy change of some process, there is no call to invoke the second law of thermodynamics.flyingpig said:How could charges move on its own such that it wants to go to equilibrium? I am getting "off-topic" here, but this seems to violate 2nd law of thermodyanmics. Why would charges want equilibrium instead of chaos?
Not really. \mathbf{E} = 0 is a perfectly valid value of an external electric field. When your book says "...in an external electric field E," that includes the possibility \mathbf{E} = 0. So what I was saying was, think through the derivation given in your book and convince yourself that it works even when \mathbf{E} = 0.flyingpig said:If the external field is 0, then there is no external field...