P3X-018
- 144
- 0
In order to get a "feeling" of the sharpness of the multiplicity function, for a system of 2 solids (A & B) with N quantum oscillators in each, in the high-temeperature limit (that is the total number of energy units q is much larger than N), it is approximated as a Gaussian as [Shroeder, eq. (2.27), 1999],
\Omega(x) = \Omega_{max}\,e^{-4Nx^2/q^2}
Where x comes from that if q = q_A + q_B then q_A = q/2 + x and q_B = q/2 - x. The width parameter of the above equation would be \sigma = \frac{q}{2\sqrt{2}N} around x = 0 (q_A = q_B).
Now how can the function be called "sharp near it's peak", when this width parameter is such a huge number by this assumption that is q >> N?
This was used to explain that only a very small number of macrostates have a reasonable chance of occurring, but how can this be, if the width is so great?
\Omega(x) = \Omega_{max}\,e^{-4Nx^2/q^2}
Where x comes from that if q = q_A + q_B then q_A = q/2 + x and q_B = q/2 - x. The width parameter of the above equation would be \sigma = \frac{q}{2\sqrt{2}N} around x = 0 (q_A = q_B).
Now how can the function be called "sharp near it's peak", when this width parameter is such a huge number by this assumption that is q >> N?
This was used to explain that only a very small number of macrostates have a reasonable chance of occurring, but how can this be, if the width is so great?
Last edited: