Since \theta goes from 0 to 2\pi, if we allowed \phi to go also from 0to 2\pi some points would have <b>two</b> descriptions. For example, \theta= 3\pi/2, \phi= \pi/4 and \theta= \pi/2, \phi= 7\pi/4, \rho and fixed value, say 1, designate the same point.<br />
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You can see that by converting to Cartesian coordinates: x= \rho cos(\theta) sin(\phi), y= \rho sin(\theta) sin(\phi), z= \rho cos(\phi).<br />
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\rho= 1, \theta= 3\pi/2, \phi= \pi/4 gives x= 1(0)(\sqrt{2}/2)= 0, y= 1(-1)(\sqrt{2}/2)= -\sqrt{2}/2 and z= 1(\sqrt{2}/2)= \sqrt{2}/2.<br />
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\rho= 1, \theta= \pi/2, \phi= 7\pi/4 gives x= 1(0)(-\sqrt{2}/2)= 0, y= 1(1)(-\sqrt{2}/2)= -\sqrt{2}/2, and z= 1(\sqrt{2}/2)= \sqrt{2}/2.