Yes, your solutions for both parts (a) and (b) are correct. Good job!

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Homework Help Overview

The problem involves the Cobalt-60 isotope, specifically its half-life and activity calculations. The original poster seeks to determine the activity of 1μg of Cobalt-60 and the age of a 10μg sample based on its activity.

Discussion Character

  • Exploratory, Assumption checking, Problem interpretation

Approaches and Questions Raised

  • Participants discuss the calculation of activity using the formula involving moles and half-life. There are questions about the correct interpretation of the mass of Cobalt and whether the calculations pertain to Co-60 or natural cobalt. Some participants suggest recalculating based on the correct mass for activity.

Discussion Status

There is ongoing exploration of the calculations and assumptions, particularly regarding the number of moles and the mass of Cobalt used in the activity calculations. Some participants provide corrections and seek clarification on specific points, indicating a productive dialogue without a clear consensus.

Contextual Notes

Participants note discrepancies in the understanding of the mass conversions and the implications of using different isotopes. The original poster's problem statement does not specify whether to consider Co-60 or natural cobalt, leading to further questioning and recalculations.

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The problem statement
The Cobalt-60 isotope is often used in medicine. It has a half-life of 5.25 years.
a) What is the activity of 1μg Cobalt in Bq (decays/second)?
b) You find a sample of Cobalt that has a mass of 10 µg and has an activity of 5.0MBq. How old is that sample?

This problem was translated from Swedish.

The attempt at a solution
a)
Activity is given by:
## A_{Bq}= n N_A \frac{ln(2)}{t_{\frac{1}{2}}} ##
where ## t_{\frac{1}{2}} = 1.656 \cdot 10^8 ## since ## 5.25 years =1.656 \cdot 10^8 seconds ## and ##N_A## is avogados constant which is ## 6.022×10^{23} mol^{−1} ## but what is n?

I guess that that is the amount of moles in 1μg Cobalt. Wolfram tells me its
## 1.6968366×10^{-8} mol ##

Thus the activity is
## A_{Bq}= n N_A \frac{ln(2)}{t_{\frac{1}{2}}} = 1.6968366 \cdot 10^{-8}\cdot 6.022\cdot10^{23}\cdot \frac{ln(2)}{1.656 \cdot 10^8}=
4.27707 \cdot 10^7##

b)
## A(t) = A_0 0.5^{\frac{t}{ t_{\frac{1}{2}} }} ##
where
A(t) = 5.0MBq
A(0) is the activity of 1μg Cobalt
##t_{\frac{1}{2}}## = ## 1.656 \cdot 10^8 ##

## A(t) = A_0 0.5^{\frac{t}{ t_{\frac{1}{2}} }} \\ 5.0 \cdot 10^6 = 4.27707 \cdot 10^7 \cdot 0.5^{\frac{t}{ 1.656 \cdot 10^8} } \\ t =5.12801×10^8 s ##
Which is about 16.26 years.

Is that solution correct?
 
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The activity of 1 gram of Cobalt-60 is 44 TBq, so 44 trillion Bq. The activity of a μg (microgram) of Cobalt-60 would be 44,000,000,000,000 divided by 1,000, which is 44,000,000,000 (44 billion Bq). So the answer to part a): The activity of 1 microgram of Cobalt-60 is 44 billion (44,000,000,000) Bq.

I'm afraid I can't help with part b) though. Hope this helped.
 
Metals said:
The activity of 1 gram of Cobalt-60 is 44 TBq, so 44 trillion Bq.
Approximately, but looking that up is certainly not the intended solution if the half-life is given.
Also note that a gram has 1 million microgram, not 1000.

@Rectifier: Correct.
 
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mfb said:
Approximately, but looking that up is certainly not the intended solution if the half-life is given.

@Rectifier: Correct.
Thank you!
 
Rectifier said:
Is that solution correct?
Works.
 
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mfb said:
Approximately, but looking that up is certainly not the intended solution if the half-life is given.
Also note that a gram has 1 million microgram, not 1000.

@Rectifier: Correct.

Apologies, thanks for the correction.
 
For part a), did you find the number of moles for Co-60 or Co-59 (natural cobalt)?

For part b), should A0 be for 1 ug or 10 ug?
 
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insightful said:
For part a), did you find the number of moles for Co-60 or Co-59 (natural cobalt)?

For part b), should A0 be for 1 ug or 10 ug?
Good points. I should have checked the numbers more carefully.
 
insightful said:
For part a), did you find the number of moles for Co-60 or Co-59 (natural cobalt)?

For part b), should A0 be for 1 ug or 10 ug?
a) that was the natural cobalt its not specified in the problem :(
b) ah darn, I guess I have to recalculate A_0 for 10 micro-grams. Is it just 10 times bigger by any chance?
 
  • #10
Rectifier said:
a) that was the natural cobalt its not specified in the problem :(
b) ah darn, I guess I have to recalculate A_0 for 10 micro-grams. Is it just 10 times bigger by any chance?
Bingo!
 
  • #11
I am not entierly sure about what to do with a) thoug? Any tips?
 
  • #12
Rectifier said:
I guess that that is the amount of moles in 1μg Cobalt. Wolfram tells me its
1.6968366×10−8mol 1.6968366×10^{-8} mol
Just correct this using the result for M from your other thread.
 
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  • #13
Rectifier said:
a) that was the natural cobalt its not specified in the problem :(
It is, you have pure Co-60.
 
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  • #14
Attempt 2 :D

a)

## A_{Bq}= n N_A \frac{ln(2)}{t_{\frac{1}{2}}} ##
## t_{\frac{1}{2}} = 1.656 \cdot 10^8 ##
##N_A = 6.022 \cdot 10^{23} mol^{−1} ##
## n = \frac{n}{M} = \frac{10^{-6}}{59.933817059} = 1.668507 \cdot 10^{-8} ##

## A_{Bq}= n N_A \frac{ln(2)}{t_{\frac{1}{2}}} = 1.668507 \cdot 10^{-8} \cdot 6.022 \cdot 10^{23} \cdot \frac{ln(2)}{1.656 \cdot 10^8}= 4.20566 \cdot 10^7##b)
## A(t) = A_0 0.5^{\frac{t}{ t_{\frac{1}{2}} }} ##
where
A(t) = 5.0MBq
##t_{\frac{1}{2}} = 1.656 \cdot 10^8 ##

A(0) is the activity of 10μg Cobalt
## n = \frac{n}{M} = \frac{10 \cdot 10^{-6}}{59.933817059} = 1.6685 \cdot 10^{-7}## (turns out activity of 1μg * 10 = activity of 10μg)

## A_{Bq} = n N_A \frac{ln(2)}{t_{\frac{1}{2}}} \\ A_{Bq} = 1.6685 \cdot 10^{-7} 6.022 \cdot 10^{23} \frac{ln(2)}{1.656 \cdot 10^8} = \\ A_{Bq} = 4.20564 \cdot 10^8##

## A(t) = A_0 0.5^{\frac{t}{ t_{\frac{1}{2}} }} \\ 5.0 \cdot 10^6 = 4.20564 \cdot 10^8 \cdot 0.5^{\frac{t}{ 1.656 \cdot 10^8 }} = 1.05889 \cdot 10^9 s ##
Or also 33.58 years

Is this right then? :)
 

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