Andrew Mason said:
If an expanding gas does work then it is not a free expansion. If it does work it cools but the gas that it does work on warms. There can be no net cooling. It is prohibited by the second law of thermodynamics.
Think of the individual parts as locked up in balloons. One balloon goes up, containing hot, wet air, and another one, containing dry, cool air, goes down. The air in the rising balloon will expand, and cool adiabatically, and the balloon going down will be compressed and will adiabatically heat. If both movements compensate, all the other air will not be compressed or expanded, will at most be horizontally displaced, and will not undergo any effect.
All convection does is lower the temperature gradient by mixing the air. It does not alter the average temperature of the air. We are talking about convection in the troposphere which extends up to about 60,000 feet (11 miles or 17 km) and an existing thermal gradient of 6.5 Kelvin/ km. Chilingar is suggesting that additional CO2 will increase the average temperature of the atmosphere but cause more convection so that smaller thermal gradient results in an actual decrease of temperature at the surface.
I don't think that there will be an actual *cooling* but as I said, I haven't studied that paper. I'm just talking in general about convection. If convection MIXES air, then there is no convection! It would then be diffusion. Convection is the flow within flux tubes of air in the vertical direction, driven by a density gradient (itself induced by composition - water vapor - or temperature). Of course, there will be *some* mixing due to microturbulence, and there will be *some* conduction. But I take it that you can consider convection essentially as a loopy flow with "air bubbles" going up, and other "air bubbles" going down as if they were adiabatically insulated, like in balloons.
So IMO, convection cannot do anything else but *reduce* the greenhouse effect as compared to a static atmosphere. If Chilingar claims that it *overcompensates* and actually leads to a cooling, then I should study his argument, but it is not my point. My point is simply that convection IS a more efficient way to cool the surface than *just* radiation transport through a static grey atmosphere, and as such, when taken into account, will lead to some diminishing of the greenhouse effect as compared with a non-moving atmosphere.
Chilingar has problems explaining how his model fits Venus. Does the 95% CO2 atmosphere of Venus cool the surface of Venus? Venus has a very high albedo factor of .75 (compared to Earth's .3). Although its solar irradiation is about double Earth's (2614 watts/m^2 versus 1367 for earth), the albedo results in a lower blackbody temperature (231 K or - 42 C versus 255K for earth). But, in fact the surface temperature of Venus is much higher (750 K!). At an altitude of 100 km the temperature goes down to 180K. This means it has an average temperature gradient of 5.7 degrees K per km. compared to Earth's 6.5. But this slightly lower gradient certainly does not result in a lower surface temperature.
Chilingar explains Venus by suggesting that chemical reaction in the lower troposphere on Venus are creating a continuous heat source that heats the surface from something less than its blackbody temperature to 750 K! He just throws this out as if it was a proven fact!
This appears to be news to NASA.
As I said, I'm not arguing Chilingar's paper, and if that claim is there, it would be very dubious indeed.
Just a single remark concerning Venus, which just occurs to me right now, and not with much thought behind it: it is funny that the vertical gradient on venus and Earth are similar, given the totally different situations. That could mean that there is a kind of maximum gradient in the atmosphere above which strong feedback mechanisms such as convection lock up the maximum gradient. As such, there is a maximum greenhouse effect for a given atmospheric thickness (pressure).