How is saturation pressure different than vapor pressure?

AI Thread Summary
The discussion clarifies the concepts of vapor pressure and saturation pressure. Vapor pressure refers to the pressure exerted by a substance as it evaporates or sublimates at a specific temperature and can be calculated using the Antoine Equation. It is measured at the interface between the substance and the atmosphere or anywhere in the system if it is at equilibrium. Saturation pressure, on the other hand, assumes that the substance has completely vaporized to its equilibrium point and can be measured in any gaseous part of the system. The key distinction lies in the state of equilibrium; vapor pressure is measured at the interface, while saturation pressure reflects the maximum pressure achievable when the system is at equilibrium.
pa5tabear
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I think I understand, but I want to make sure.

The vapor pressure of a substance is the pressure of the substance evaporating/sublimating at a given temperature and can be calculated using the Antoine Equation. This must be measured at the interface of the substance and atmosphere, or if the system is at equilibrium, it could be measured anywhere in the system.

The saturation pressure assumes that the substance has fully vaporized to its equilibrium point. It could be measured at any gaseous part of the system.

They are almost the same, right? The difference is just whether the system is at equilibrium?
 
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If I understand your question correctly - yes. We just assume pressure has its maximum possible value at the interface, no matter what is going on in other parts of the system. This is equivalent of assuming there is an equilibrium on the surface.
 
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