Boltzmann Definition and 192 Threads

I don't know how to integrate the Maxwell-Boltzmann distribution without approximation or help from Maple. Given the Maxwell-Boltzmann distribution: f(v) = 4\pi\left[\frac{m}{2\pi kT}\right]^{3/2}v^2\textrm{exp}\left[\frac{-mv^2}{2kT}\right] Observe the appearance of the Boltzmann factor...

I don't know how to integrate the Maxwell-Boltzmann distribution without approximation or help from Maple. Given the Maxwell-Boltzmann distribution: f(v) = 4*pi*[m/(2*pi*k*T)]^(3/2)*v^2*exp[(-m*v^2)/(2*k*T)] Observe the appearance of the Boltzmann factor exp[(-m*v^2)/(2*k*T)] with E =...

Below is part of derivation of the Boltzmann equation in an electric and magnetic field. I don't understand how to arrive at the bottom equation though. It is known that the dependence of the original distribution function is the given. My idea is to use chain rule but I don't see how to get a...

A system has two non-degenerate energy levels E1 and E2, where E2>E1>0. The system is at tempreture T. The Average energy of the system is = E1+E2e^(-B*deltaE) / 1+e^(-B*deltaE) where deltaE= E2 -E1 and B=1/kT (k=Boltzmann constant). show that for very low temperatures kT<<deltaE, average...

A certain particle is interacting with a reservoir at 500 k and can be in any four possible states. The ground state has energy 3.1 eV and three excited states all have the same energy. what is the probability that the particle is in ground state? what is the probability that the particle is in...

This article insinuates that the physics community had forgotten Gibbs entropy long ago and has used Boltzmann entropy since. Isn't this nonsense? For me it was always clear that Boltzmann entropy is problematic...

The question is in the image file. I am stuck, I don't know how to start. Can someone guide me please?

Does anyone know if Max Planck knew about the Boltzmann distribution before he published his results in 1900? Also, when Planck introduced h, did he also give the value?

Suppose a set X describes the possible states of some system, and suppose a function x\mapsto E(x) tells the energy level of each state. At temperature T the Boltzmann-measure, which will be the probability measure describing the state of the system, is obtained by formula dp(x) =...

Can anybody point me to a rough calculation of the probability of a disembodied brain appearing from a random fluctuation vs the probability of a brain evolving in a vary large random fluctuation? I'm an eternalist. I find it easier to accept the ridiculous idea that the universe was always...

Homework Statement You will recall from our discussion of the Franck-Hertz experiment that the energy difference between the first excited state of mercury and the ground state is 4.86 eV. If a sample of mercury vaporized in a flame contains 1.06×1020 atoms in thermal equilibrium at 1563 K...

I'm puzzled by the appearance in the literature of 2 conflicting forms: P(E)=√(E)*exp(-E), which I understand as derived from the Maxwell distribution for speed. It is a chi -square distribution with 3 degrees of freedom. P(E)=exp(-E), which seems wrong to me. But it is not simply a...

Homework Statement A system in thermal equilibrium at temperature T consists of N particles that have two energy states separated by an energy Δε. If the number of particles in the two states is N1 and N2, show that: N{1} = N(\frac{1}{1+exp(-Δε/k{B}T})) and N{2} =...

Homework Statement Solve the Boltzmann equation for a homogeneous plasma with not external forces present when the collision term is \frac{\partial f(v,t)}{\partial t} = -\nu (f(v,t) - f_0(v)), where \nu and f_0 are constants. Homework Equations Boltzmann equation \frac{\partial...

According the the kinetic theory of gases, molecules moving along the x direction are given by Σx= (1/2) mv^2, where m = mass and vx is the velocity in the x direction The distribution of particles over velocities is given by the Boltzmann law p(x)=e^[(-mv^2)/ekT] where velocities range from...

At 293K, helium atoms have a root mean square speed of about 1.35 km/s, whereas escape velocity at the Earth's surface is about 11km/s. Explain why is it nevertheless possible for helium atoms to escape from the Earth into space. Is it because near the top of the atmosphere the temperature...

Homework Statement Okay i want to ask 2 questions. Question 1 Hyperstoichiometric compound Al3O has a vibrational energy spacing of 3.08x 10^-21J how many molecules are present in the ground state at 300k and 3000K Question 2 Calirimetric data for protein unfolding yielded following...

Hi PFers. I am interested in Maxwell Boltzmann Distribution. I have searched in Internet for the derivation but I am not satified with them. Can somebody show me the way to derivate it? Thanks. ψ(v)=(m/2*pi*kT)^(3/2) e^(-mv^2/2kT)

From theory, we know that Boltzmann entropy for a given distribution, defined through a set of occupancy numbers {ni}, of the macrostate M, is given by: S=k log(Ω{ni}) where omega is the number of microstates for the previously given set of occupancy number, {ni} . Assuming that the system...

Hello! I have two questions for knowledge. Q) Explain under what conditions Maxwell Boltzmann and Fermi Dirac statistics are applied on free electrons. Q) Explain each parameter of Boltzmann Transport's equation. Thank you in advance. :-)

Homework Statement The three quantities Vmost probable, Vaverage, and Vrms, are not the same for the Maxwell speed distribution in 3D. If you restrict the gas to only be one dimensional, are these three quantities equal to each other? Justify your answer with a short explanation. Homework...

Hello, Please could someone explain to me about Boltzmann distribution and Fourier transformation? or point me in the direction of some really really easy-to-understand guide? I need to understand it for biology - to understand NMR and mass spectrometry. Thanks.

Im recently studying Boltzmann Constant for Landauer's principle. I wondered is there a volume for that? What's the units they use(cm or m) when we derive the Boltzmann constant? I've been looking through the internet but I found nothing. Any Help? Thanks

Hey Guys, so I had a longish discussion with colleagues and on reddit about thermal equilibrium and the sun and how you cannot heat up anything above the surface temperature of the sun using clever mirrors and stuff. However, somebody came up with Napkin calculations of the Stefan Boltzmann...

Dear All I have a question about the validity of Maxwell Boltzmann velocity distribution in the case of nanoscale systems. When you consider a nanoscale system such as flow of water molecules (less than 100 molecules) through a carbon nanotube or graphene sheet, is it possible to expect a...

In Reif's book Fundamentals of Statistical and Thermal Physics, he labels two formulas as the Stefan-Boltzmann Law. They are both involve T^4 but the constant is different. In one, on page 376, the law is given as (pi2/15)*(kT)4/(c*hbar)3. The other, on page 388, is...

Hi, I see that Boltzmann constant comes in different forms like: k=8.62*10-5 eV/K and also k=1.38*10-23J/K. Which one should I use in , say formula for intrinsic carrier concentration ni = sqrt(Nc*Nv)*e-Eg(T)/2kT ?

I remember I read somewhere about the Boltzmann distribution that it is only valid for high temperatures. Why is that?

Consider a resevoir of N atoms in contact with a single atom. Obviously, if the atom is in a high energy state then the multiplicity left for the resevoir is significantly lower. So this is in agreement with the fact that looking at the single atom, the probability for the ground state is very...

Why is the Boltzmann distribution for a collection of atoms independent of their total energy? (it only depends on their temperature) One would assume that if the energy is high there'd be a greater tendency to be in excited states or am I wrong?

Homework Statement Use the Boltzmann distribution function to calculate the temperature at which 1.00% of a population of photons will have energy greater than 1.00 eV. The energy required to excite an atom is on the order of 1 eV. The Attempt at a Solution I attached my attempt but...

What is the Boltzmann distribution look like if we have a mix of two gasses with very different molecular weights? Say hydrogen at 2 amu and xenon at 132 amu. Do they have equal average momentum and hence the hydrogen has an average velocity 66 times the velocity of the xenon and an energy...

Hello everyone! I have been on this website for quite a while, and found some interesting answers to many questions, and I decided to create an account to seek you help with a particular issue I encountered in my assignment. Please have a read, and thank you for any input! Homework...

Hello, I'm working of the Boltzmann equation to simulate a partially ionized plasma, but I'm having troubles to solve the collision term. I'm using a splitting technique for the advection in the phase-space, but I'm quite stuck in the collision term. Any recommendations?

hi everyone, consider two different masses of ideal gases with different molar masses, we're putting them in a uniform gravitational field and wait until they come to their equilibrium states. how would the density distribution change with height in this case? ( i came out with this question...

Why I can't calculate the same answer as the solution below? I use the value as what the below solution showed. Q: Where Nj is the number of atoms in excited state, No is the number of atoms in the ground state, Pj and Po are constants determined by the number of states having equal energy...

Homework Statement The relative population of two atomic population states in equilibrium is given by Boltzmann Distribution: n1/n0 (proportional to) e^(-ε/(κT)) , where ε is the energy difference between the two states, T is the temperature and κ is the Boltzmann constant = (1.38 x...

kT where k is Boltzmann constant times the absolute temperature. what happen if the temperature is a variable?

For N(E)=Aexp(-E/kT), I know that N(E) is the no. of particles with a certain energy E, but why does integrating N(E) from 0 to infinity equal to 1? Although I realize that it means that there is 100% probability to find a particle in this range, I want to know why summing up all no. of...

Boltzmann transport equation & drift-diffusion equation ~ Plz help me! 1. From the Boltzmann transport equation, derive the energy conservation equation for mass conserving particles. Use the momentum equation to subtract the mechanical energy component, and then derive the equation for...

how do i find the luminosity of a star

Hello. Do you know any textbook about Statistical Mechanics that discusses Boltzmann Transport Equation? It is not discussed in the textbooks that I know. Thank you.

I don't remember why the Boltzmann constant is the perfect number that let's us convert the log of the multiplicity to a unit that works with other SI units. I understand that this constant was "given" units of J/K but why does it work exactly to convert a rather odd made-up number (log of the...

Homework Statement The first excited state of Ca is reached by absorption of 422.7-nm light. • Find the energy difference (kJ/mol) between ground and excited states. • The degeneracies are g*/g0 = 3 for Ca. Find N*/N0 at 2 500 K. • By what percentage will N*/N0 change with a 15-K rise in...

Show that the Maxwell - Boltzmann distribution integral: the integral of f(v) dv from zero to infinity is equal to one. I know what the formula is but I am unsure on how to approach this problem. Please help in any way. Thanks. Also, I know that the integral is the area under the curve of...

Homework Statement Compute the mean energy and mean square energy of a free particle using the Boltzmann distribution. Homework Equations The Attempt at a Solution I calculated the mean energy to be 3/2 kT by computing the mean square velocity directly from the Boltmann...

hi, i've never posted on here before but would appreciate any help given for this question. The scattering term (4th term) in the Boltzmann transport equation contains a double integral. What are you integrating over in each case and why is this? this may be a simple question but...

I read http://en.wikipedia.org/wiki/Maxwell%E2%80%93Boltzmann_distribution#cite_note-0 In formula 7 we obtain proportionaly to E^1/2 and exp(-E). But I expect proportionaly to E^-1/2 and exp(-E). Where I am wrong?

The Stefan-Boltzmann law is as follows: The energy radiated by a black body radiater per second per unit area is directly proportional to the fourth power of the absolute temperature. Equation: I = σT^4 Is it possible to explain this law by means of classical physics only? If so...

Hi guys. I'm new here and pretty much a layman when it comes to physics and astronomy. I came across this hypothesis a few months ago, but have been looking at it the last few days. Anyway, I'm hoping you guys know about this so you can help me. Search wikipedia for it if not. I'm not...