In order to apply perturbation theory to the ψ_{200} and ψ_{210} states, we have to solve the matrix eigenvalue equation.
Ux=λx where U is the matrix of the matrix elements of H_{1}= eEz between these states.
Please see the matrix in attachment 1.
where <2,0,0|z|2,1,0>=<2,1,0|z|2,0,0>=3a_{o}...