Calculating Heat Energy Released in Ozone Decomposition Reaction

Click For Summary

Discussion Overview

The discussion revolves around calculating the heat energy released during the decomposition of ozone (O3) into oxygen (O2) and atomic oxygen (O) under ultraviolet light. Participants explore various methods and considerations related to this exothermic reaction, including bond energies and resonance structures.

Discussion Character

  • Exploratory
  • Technical explanation
  • Mathematical reasoning

Main Points Raised

  • One participant questions how to calculate the heat energy released in the ozone decomposition reaction, noting it is exothermic.
  • Another participant suggests that the energy released could be estimated based on the loss of a covalent bond between two oxygen atoms, proposing a value of 146 kJ/mol.
  • A different participant introduces the idea that ozone has resonating structures, which may influence its stability and the energy released during the reaction.
  • Another participant proposes a method involving the heat of formation for ozone and the energy required to create mono-atomic oxygen, suggesting this could provide a rough estimate or sanity check for the energy calculations.

Areas of Agreement / Disagreement

Participants express various hypotheses and methods for estimating the heat energy released, but there is no consensus on a definitive approach or value. Multiple competing views remain regarding the factors influencing the energy calculations.

Contextual Notes

Some assumptions regarding the preparation of ozone and the energy calculations are not fully detailed, and the discussion does not resolve the mathematical steps involved in deriving the estimates.

rhenretta
Messages
65
Reaction score
0
I have been doing some research on ozone recently, and I have a question that none of my resources have answered...

The following reaction is an exothermic reaction, but how would I calculate the amount of heat energy is released?

O_{3} \underbrace{\rightarrow}_{uv\ light} O_{2} + O

where uv wavelength < 290nm
 
Chemistry news on Phys.org
Am I on the right track? I looked up the energy of the covalent bonds, and in the destruction of ozone, there is a loss of a single covalent bond between 2 oxygen atoms. Therefore the energy released would be 146 kJ / mol?
 
not sure but ozone has resonating structures so that might add something to its stability and hence can effect the energy released
 
Would not a good guess be the heat of formation for ozone minus the energy required to split O2 (that is, create mono-atomic oxygen)? I am assuming that the O3 is prepared by passing an electric arc through air.

1. O2 --Energy--> O + O

2. O2 + O ---> O3

Now, if you do otherwise derive an estimate, then you also have an estimate of the energy required for Equation [1], or at least, a sanity check.
 

Similar threads

  • · Replies 1 ·
Replies
1
Views
2K
  • · Replies 8 ·
Replies
8
Views
3K
  • · Replies 3 ·
Replies
3
Views
5K
  • · Replies 14 ·
Replies
14
Views
5K
  • · Replies 1 ·
Replies
1
Views
2K
  • · Replies 4 ·
Replies
4
Views
3K
  • · Replies 131 ·
5
Replies
131
Views
10K
Replies
6
Views
6K
Replies
1
Views
2K
  • · Replies 14 ·
Replies
14
Views
4K