Cartesian coordinates uniquely represent points as ordered pairs (x,y) based on their distances from two perpendicular axes, ensuring distinct mappings for each coordinate. In contrast, polar coordinates can lead to non-unique representations, as multiple polar coordinates can correspond to the same point, such as (r=0, θ=0) and (r=0, θ=π/3). While Cartesian coordinates excel in precision and efficiency for mathematical and physical calculations, they do not account for direction. Polar coordinates, however, incorporate both distance from the origin and angle, providing a more intuitive understanding of a point's location. Ultimately, the choice between these systems depends on the specific context and requirements of the task at hand.