Decomposition temperature of ZnSe:Cl crystal

In summary, the decomposition temperature of ZnSe:Cl crystal is the temperature at which the crystal begins to break down into its constituent elements, zinc, selenium, and chlorine. It is typically around 700-800°C and can be determined through methods such as thermal analysis, differential scanning calorimetry, and thermogravimetric analysis. Factors such as impurities, heating rate, and atmosphere can affect the decomposition temperature. It is important as it determines the maximum temperature for the crystal's use in high-temperature applications. The decomposition temperature can be increased by improving purity, optimizing growth process, reducing defects and impurities, and using protective coatings or encapsulation methods.
  • #1
JeffFang
1
0
Any one knows what the decomposition temperature of ZnSe semiconductor doped with Cl is? I am doing some annealing with a simple equipment but worring about the volatilization of Cl, which would be dangerous.
Thanks a lot!
 
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  • #2
I stumbled across an abstract of paper with temperatures at 250-300°C.

Try this link - ]Ti/Pt/Au Ohmic Contacts to n-Type ZnSe [/url] - unfortunately, it's only an abstract and registration with the Japanese Journal of Applied Physics is required to downlaod the pdf file.
 
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  • #3


The decomposition temperature of ZnSe:Cl crystal can vary depending on the specific doping concentration and the method of preparation. However, generally speaking, the decomposition temperature of ZnSe:Cl is around 600-700 degrees Celsius. It is important to carefully control the annealing temperature and time to prevent the volatilization of Cl, which can indeed be dangerous. It is recommended to consult the supplier or literature for specific guidelines on the appropriate annealing conditions for your ZnSe:Cl crystal.
 
1)

What is the decomposition temperature of ZnSe:Cl crystal?

The decomposition temperature of ZnSe:Cl crystal is the temperature at which the crystal begins to break down into its constituent elements, zinc, selenium, and chlorine. This temperature varies depending on the purity and composition of the crystal, but it is typically around 700-800°C.

2)

How is the decomposition temperature of ZnSe:Cl crystal determined?

The decomposition temperature of ZnSe:Cl crystal is determined through various methods such as thermal analysis, differential scanning calorimetry (DSC), and thermogravimetric analysis (TGA). These techniques measure the changes in the physical and chemical properties of the crystal as it is heated, allowing researchers to determine the temperature at which decomposition occurs.

3)

What factors can affect the decomposition temperature of ZnSe:Cl crystal?

The decomposition temperature of ZnSe:Cl crystal can be affected by factors such as impurities in the crystal, the rate of heating, and the atmosphere in which the crystal is heated. Other factors such as crystal size, defects, and strain can also influence the decomposition temperature.

4)

Why is the decomposition temperature of ZnSe:Cl crystal important?

The decomposition temperature of ZnSe:Cl crystal is important because it determines the maximum temperature at which the crystal can be used without undergoing decomposition. This information is crucial for applications that require high-temperature operation, such as in lasers and optical devices.

5)

Can the decomposition temperature of ZnSe:Cl crystal be increased?

Yes, the decomposition temperature of ZnSe:Cl crystal can be increased by improving the purity of the crystal, optimizing the crystal growth process, and reducing the presence of defects and impurities. Additionally, the use of protective coatings or encapsulation methods can also increase the stability and decomposition temperature of the crystal.

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