Do rotational degrees of freedom contribute to temperature?

AI Thread Summary
Rotational degrees of freedom in gases contribute to the internal energy but not directly to the measurement of temperature. When heating a polyatomic gas at constant volume, its heat capacity is higher than that of a monatomic gas, resulting in a smaller temperature increase for the same energy input. The temperature is related to the average kinetic energy of all thermally excited modes, not just translational kinetic energy. The equipartition theorem indicates that energy is distributed among all degrees of freedom, but temperature itself is not a sum of these contributions. Therefore, when measuring temperature, one is assessing the average energy associated with all degrees of freedom, including rotational and vibrational, rather than just translational energy.
  • #51
I couldn't understand this?
 

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  • #52
Death eater said:
I couldn't understand this?
The internal energy resides partly in the motions of the molecules and partly in the vibrations of atoms within the molecules.
When you measure the temperature you are measuring the motions of the molecules.
If a high proportion of the energy is in motions within molecules then you will need to raise the internal energy more for the same measured rise in temperature.
 
  • #53
haruspex said:
The internal energy resides partly in the motions of the molecules and partly in the vibrations of atoms within the molecules.
When you measure the temperature you are measuring the motions of the molecules.
If a high proportion of the energy is in motions within molecules then you will need to raise the internal energy more for the same measured rise in temperature.
Please check the photo I posted?
 
  • #54
Death eater said:
Please check the photo I posted?
I did, and my previous reply paraphrases what the book says.
 
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