Equalibrium & Le chatliers principle

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In summary, increasing the concentration of A in the reaction A + B <==> C + D at equilibrium will cause a shift towards the right side of the equation and a decrease in concentration of B. The effect of increasing temperature on the system depends on whether the reaction is endothermic or exothermic. In an endothermic reaction, increasing the temperature will cause the system to oppose the change and reduce the temperature, following Le Chatelier's principle. In an exothermic reaction, increasing the temperature will cause an increase in yield.
  • #1
faisal
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When your increase the concentration do you increase the yield of products?
And if you increase temperature will the system oppose this change and reduce the temperature applying le-chitaliers principle, and how much yield would you get if temperature is increased/reduced?
 
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  • #2
Given
A + B <==> C + D at equilibrium
If you increase the concentration of A, there will be a shift in equilibrium towards the right side of the equation and a decrease in concentration of B.
For the temperature it depends on whether or not the reaction is an exothermic reaction or an endothermic reaction. I'll let you think about this one...
Endothermic reaction:
heat + A + B <==> C + D
Exothermic reaction:
A + B <==> C + D + heat
 
  • #3


Equilibrium and Le Chatelier's Principle are important concepts in chemistry that help us understand how a system responds to changes in conditions. In an equilibrium system, the forward and reverse reactions are occurring at the same rate, resulting in a constant concentration of reactants and products. Le Chatelier's Principle states that when a system in equilibrium is subjected to a change in conditions, it will respond in a way that minimizes the effect of that change.

In terms of increasing the concentration of reactants or products, Le Chatelier's Principle predicts that the system will shift in the direction that reduces the concentration of the added species. This is because an increase in concentration disrupts the equilibrium and the system will try to restore balance by producing more of the product or consuming more of the reactant. Therefore, increasing the concentration of a reactant will result in an increase in product yield, and vice versa.

When it comes to changes in temperature, Le Chatelier's Principle also applies. In an exothermic reaction, increasing the temperature will shift the equilibrium towards the reactants to consume the excess heat. On the other hand, decreasing the temperature will shift the equilibrium towards the products to release more heat. In an endothermic reaction, the opposite effects will occur. Therefore, the system will always try to oppose the change in temperature by shifting the equilibrium in the direction that minimizes the effect of the temperature change.

The amount of yield obtained when the temperature is increased or reduced will depend on the specific reaction and its equilibrium constant. Generally, increasing the temperature will result in a higher yield if the reaction is exothermic, and a lower yield if the reaction is endothermic. The opposite is true for decreasing the temperature. However, it is important to note that there are other factors that can also affect yield, such as the concentration of reactants and the presence of catalysts.

In conclusion, Le Chatelier's Principle predicts that a system in equilibrium will respond to changes in conditions in a way that minimizes the effect of that change. Increasing the concentration of a reactant will result in an increase in product yield, while increasing or decreasing the temperature will affect yield differently depending on the nature of the reaction. It is important to carefully consider all factors and conditions when trying to maximize product yield in a chemical reaction.
 

1. What is equilibrium and why is it important in chemistry?

Equilibrium is a state in which the forward and reverse reactions of a chemical reaction are occurring at equal rates, resulting in no net change in the concentrations of reactants and products. This is important because it allows us to predict and understand how a system will behave over time.

2. How does Le Chatelier's principle explain changes in equilibrium?

Le Chatelier's principle states that when a system at equilibrium is subjected to a stress, it will shift in a direction that reduces that stress. For example, if the concentration of a reactant is increased, the equilibrium will shift to the right to consume more of that reactant and restore equilibrium.

3. Can you give an example of Le Chatelier's principle in action?

One example is when carbon dioxide gas is dissolved in water to form carbonic acid. If the concentration of carbon dioxide gas is increased, the equilibrium will shift to the left, producing more carbonic acid and lowering the pH of the solution.

4. What factors can affect equilibrium in a chemical reaction?

The factors that can affect equilibrium include changes in concentration, pressure, temperature, and the presence of a catalyst. In general, any change that affects the rate of the forward or reverse reactions can also affect the equilibrium.

5. How can we manipulate equilibrium to favor the formation of a desired product?

We can manipulate equilibrium by changing the conditions of the reaction, such as adjusting the temperature, pressure, or concentration of reactants. We can also use a catalyst to increase the rate of the desired reaction, which can shift the equilibrium towards the formation of the desired product.

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