Final temperature real gas behaving ideally

AI Thread Summary
The discussion revolves around calculating the final temperature of a gas mixture consisting of oxygen, nitrogen, and carbon dioxide after heating with 753 kJ in a well-insulated vessel. The equation used for this calculation is based on real gases behaving ideally, specifically Eq. 3.48, which incorporates the specific heat coefficients (α, β, γ) for each gas. Participants confirm that the molar ratios of each gas can be used to find the average coefficients for the mixture. The initial temperature of the mixture is necessary for completing the calculation. The conversation emphasizes the independence of the gas components when approximating the mixture as an ideal gas.
Logan McEntire
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Homework Statement


Please consider a mixture of oxygen (1 mole), nitrogen (4 mole), and carbon dioxide (3 mole). The mixture was heated in a well - insulated vessel with 753 kJ.

Determine the final temperature if the mixture is composed of real gases behaving ideally as described by Eq. 3.48 truncated after the third term.
Q=753000 J
O2: α=3.626 β=-1.878 γ=7.055
N2: α=3.675 β=-1.208 γ=2.324
CO2: α=2.401 β=8.735 γ=-6.607
R=8.314 kJ/(kmol*K)

Homework Equations


EQ 3.48: Q/nR=α(T2-T1)+1/2β(T22-T12)+1/3γ(T23-T13)

The Attempt at a Solution


I know all the α,β,γ values for O2, N2, and CO2.
I know n=8 moles.
but I don't know the values of α, β, and γ for the mixture.
I thought of using a molar ratio of each element and multiplying that times each α, β, and γ then adding them all together but I wasn't sure if this was correct
 
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Yes, that's correct. Approximating the mixture as an ideal gas, the three components behave independently.
 
You will need to know the initial temperature.

Just to follow up on Chester's point,

##\Delta Q = \Delta U = (n_1C_{v1}+n_2C_{v2}+n_3C_{v3})\Delta T = (n_1+n_2+n_3)C_{vmix}\Delta T##

AM
 
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