Heat Transfer and the 2nd Law of Thermodynamics

AI Thread Summary
The discussion focuses on determining the initial and final pressures of water transitioning from saturated liquid to saturated vapor at 300°C, as well as calculating the heat transferred per kilogram. Participants emphasize the importance of using saturated steam tables to find the relevant pressure and specific internal energy values. The pressure at saturation for water at 300°C is identified as approximately 85.81 bar, while the superheated vapor pressure is around 8.5 MPa. Interpolation between temperature and pressure values from different tables is suggested to achieve accurate results. The conversation highlights the necessity of understanding phase changes and utilizing thermodynamic tables effectively.
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Homework Statement



Heat is transferred into saturated liquid water until it is saturated vapor. The water remains at 300 C throughout the process.

a. What is the initial pressure?

b. What is the final pressure?

c. How much heat is transferred per kg of water?

I'm having trouble with a and b. I assume i need to use the steam and compressed liquid tables, but I am not sure how to use this given info to get it.

Homework Equations



part c: energy balance gives Q/m = u1 - u2

Q = heat transfer
u = specific internal energy

I can simply use tables to find the u values once parts a and b are found.

The Attempt at a Solution

 
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What is the significance of "saturated liquid water until it is saturated vapor", i.e. this is just a change of phase from pure liquid to pure vapor.

Take a look at saturated steam tables.
 
Wouldnt i also need to know the pressure?
 
aznkid310 said:
Wouldnt i also need to know the pressure?

What must the pressure be if the water is at a saturation point?

CS
 
looking at the saturated liquid-vapor table, is it 85.81 bar?

If so, it also gives values for entropy, enthalpy... for saturated liquid and vapor. I could just use those values right?
 
aznkid310 said:
looking at the saturated liquid-vapor table, is it 85.81 bar?

If so, it also gives values for entropy, enthalpy... for saturated liquid and vapor. I could just use those values right?

Since I don't have your table I can't say. However, if the value listed for 300 C saturated water is 85.81 bar then I would say yes. Essentially you will just read it off the table since the problem tells you it is saturated. You'll need to use the super-heated vapor table for part b.

CS
 
It says saturated liquid vapor mixture.

When I am looking at the sat. vapor tables, there are a wide variety of pressures. How do i know which to use?
 
aznkid310 said:
It says saturated liquid vapor mixture.

When I am looking at the sat. vapor tables, there are a wide variety of pressures. How do i know which to use?

Most superheated vapor tables list the saturation temperature as well. So just find the one with the pressure that corresponds to 300 C and that will be the saturation pressure of the superheated vapor. Note: you may have to interpolate if 300 C is not listed.

The pressure should be around 8.5 MPa for 300 C superheated vapor based on my tables.

T= 295.01 C, P = 8.0 MPa

and

T = 303.35 C, P = 9.0 MPa

So just interpolate to find 300 C exactly.

Hope this helps.

CS
 
I have found similar temperatures: 295.06 and 311.06, but we can't interpolate directly between sets of tables, right?

So should I, say, find specific volume v in one set (at 295.09 C for example), do the same for the other, then interpolate these v and T values to find the actual v at 300C so that I can use the ideal gas equation?
 
  • #10
aznkid310 said:
I have found similar temperatures: 295.06 and 311.06, but we can't interpolate directly between sets of tables, right?

Sure you can.

CS
 
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