How does temperature in Celcius affect enthalpy in a compressed liquid?

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The discussion explores the relationship between temperature in Celsius and enthalpy for compressed liquids, highlighting a similarity between the equation Cv*T and enthalpy values from property tables. At 50°C, the calculated enthalpy using Cv (approximately 4.18) matches the tabulated hf value of 209.34 kJ/kg, while using Kelvin yields a significantly higher number. The inquiry focuses on why Celsius is applicable in this context, suggesting a potential link to the dependence of saturated water tables on Celsius. Additionally, it emphasizes the importance of understanding the reference state for zero enthalpy, which varies by table. Overall, the conversation underscores the significance of temperature units in thermodynamic calculations.
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Hello!

I was playing around with a problem and while I was doing it I noticed a similarity between

Cv*T=h by using Celcius and not Kelvin.

So if I have a compressed liquid at say 50°C, looking up at a property table I find the hf to be 209.34 kJ/kg (the pressure is considered to be low). If you take the equation Cv*T, where Cv≈4.18 and T=50°C you get 209 kJ/kg. Doing this with kelvin instead gives a much larger number.

My question is why is the relation here Celcius? Does it have something to do with the saturated water tables being Celcius dependent?
 
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MariusM said:
Hello!

I was playing around with a problem and while I was doing it I noticed a similarity between

Cv*T=h by using Celcius and not Kelvin.

So if I have a compressed liquid at say 50°C, looking up at a property table I find the hf to be 209.34 kJ/kg (the pressure is considered to be low). If you take the equation Cv*T, where Cv≈4.18 and T=50°C you get 209 kJ/kg. Doing this with kelvin instead gives a much larger number.

My question is why is the relation here Celcius? Does it have something to do with the saturated water tables being Celcius dependent?
The reference state for zero enthalpy is typically not taken as absolute zero. You have to look up in your table the specific reference state that they use for zero enthalpy. This information is usually given on the first page of the table at the very top. Or, you can look at the numbers in the table until you find a set of conditions where h is zero.

Chet
 
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Thank you very much for your informative reply! I will read more upon the subject of reference state regarding zero enthalpy so I'll hopefully get a full comprehension of this.
 
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