How is the 2nd law of thermodynamics related to the uncertainty principle?

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Discussion Overview

The discussion explores the relationship between the second law of thermodynamics and the uncertainty principle, examining whether the second law has a quantum mechanical origin or can be derived from classical systems. The conversation includes theoretical perspectives and interpretations from both classical and quantum viewpoints.

Discussion Character

  • Debate/contested
  • Conceptual clarification
  • Technical explanation

Main Points Raised

  • Some participants suggest that the second law of thermodynamics may have a quantum mechanical origin.
  • Others argue that the second law can be derived from the statistics of ideal classical bodies, asserting that quantum evolution is time symmetric.
  • A participant notes that while quantum evolution is time symmetric, it does not prevent entropy from increasing, leading to the concept of the "thermodynamic arrow of time."
  • Another participant mentions that statistical mechanics is often taught as a quantum theory, which complicates the notion of relying solely on classical bodies.
  • One participant expresses confusion over the original question, indicating that it lacks context or reference to specific statements or theories.
  • Another participant acknowledges that while the second law can be derived from classical ensembles, the behavior it relies on has a quantum mechanical origin, emphasizing the value of understanding randomness in advancing science.

Areas of Agreement / Disagreement

Participants do not reach a consensus; multiple competing views remain regarding the origin of the second law of thermodynamics and its relationship to quantum mechanics.

Contextual Notes

Some assumptions about the definitions of classical and quantum systems are not fully explored, and the discussion reflects varying interpretations of the relationship between entropy and quantum mechanics.

quantumkiko
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Does this suggest that the 2nd law of thermodynamics has a quantum mechanical origin?
 
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No, since thermodynamics can be derived from statistics of ideal classical bodies (and quantum evolution is time symmetric).
 
People have indeed shown such a relation. I noticed a professor here has posted a popularized article about this on his door (I think it may be scientific american, so I may be able to provide a link). I'll check next time I pass by his door.

cesiumfrog said:
No, since thermodynamics can be derived from statistics of ideal classical bodies (and quantum evolution is time symmetric).
Yes, quantum evolution is time symmetric. But that doesn't prevent entropy from increasing in one direction. Hence the notion of "thermodynamic arrow of time" (time increases in the direction of entropy increase).

Also, statistical mechanics is usually taught as a quantum theory (working with the multiplicity of states having the same macroscopic state values of, for instance, the total energy). So this doesn't need to be an issue of "ideal classical bodies".

Usually ideas relating entropy increase and quantum mechanics use the fact that as things interact their states become entangled.
 
quantumkiko said:
How is the 2nd law of thermodynamics related to the uncertainty principle?... Does this suggest that the 2nd law of thermodynamics has a quantum mechanical origin?

What does "this" mean?! You haven't described any statement/fact/experiment/theory to refer to!

The Second Law is derivable from classical systems, so no, I wouldn't say it has a quantum mechanical origin.
 
Mapes said:
The Second Law is derivable from classical systems, so no, I wouldn't say it has a quantum mechanical origin.
Did you read the other posts?


Anyway, I checked the professor's door and it is still up. I can't find a free link to it, but googling I did find someone who put up an editorial of the article and goes over the main points:
http://wwwrsphysse.anu.edu.au/~tas110/Teaching/Lectures/L5/Material/Lloyd06.pdf
You can get the reference to the main article from there.
 
Thanks for the link. OK, I see what you mean; the behavior on which the Second Law relies has a QM origin (because the behavior of all matter has a QM origin). My point was only that one can derive the Second Law from classical ensembles (as Gibbs did) and apply it to all sufficiently large systems with knowing any QM. But you're right; a deeper knowledge of randomness is valuable and will no doubt advance our science.
 

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