I am a contestant for the M-Prize challenge

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The M-Prize Competition challenges participants to design a spacecraft capable of reaching an altitude of at least 100 km and orbiting Earth nine times, all within a budget of $3,500. Contestants are exploring various designs, including liquid-fueled rockets based on the rockoon concept, which involves launching from a balloon. Some participants express skepticism about the feasibility of the budget, citing high costs associated with rocket components and fuel. The discussion includes humorous and sarcastic remarks about the competition's legitimacy and the challenges of space travel, with some users questioning the qualifications of the competition's organizers. There are also requests for affordable parts and advice on compliance with regulations. Overall, the conversation reflects a mix of enthusiasm, skepticism, and humor regarding the ambitious goals of the competition.
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  • #52
turbo-1 said:
Please! Quit the crap. Peroxide is not a fuel. It was used as a source of oxygen in some designs. It is a fairly heavy oxidizer compared to oxygen, and you still need some fuel to burn. This thread is a huge joke.

signerror said:

Thanks for saving me the inconvenience of enlightening turbo about advanced propulsion technology.Glad to see at least some people here are scientists.
 
  • #53
I wish you the best of luck, Iyafrady, seriously. Reach for the stars.
 
  • #54
Let me see you launch a rocket into orbit using hydrogen peroxide. This is way beyond silly. Once a vessel is in space, it is possible to use hydrazine thrusters for attitude control, and it is possible (if you have budgeted for the lift-mass of the oxidizer) to use hydrogen peroxide for attitude control. There is not a single post in this thread to suggest that you have any appreciation for the amount of thrust that it might take to put a 10g payload into orbit. Somehow, you have also lost the enthusiasm to claim that there is a M-prize, and have glommed onto the odd N-prize. Why won't a mentor put this thread out of its misery?

BTW, If I wanted to claim the fictitious M-prize, all I would have to do is machine a super-gun, load it with some trackable bullet, and point it east at a suitable elevation. It might be tough to make the bullet trackable, but it would be a heck of lot easier than constructing nano-space-craft.
 
  • #55
turbo-1 said:
Let me see you launch a rocket into orbit using hydrogen peroxide. This is way beyond silly. Once a vessel is in space, it is possible to use hydrazine thrusters for attitude control, and it is possible (if you have budgeted for the lift-mass of the oxidizer) to use hydrogen peroxide for attitude control. There is not a single post in this thread to suggest that you have any appreciation for the amount of thrust that it might take to put a 10g payload into orbit. Somehow, you have also lost the enthusiasm to claim that there is a M-prize, and have glommed onto the odd N-prize. Why won't a mentor put this thread out of its misery?

BTW, If I wanted to claim the fictitious M-prize, all I would have to do is machine a super-gun, load it with some trackable bullet, and point it east at a suitable elevation. It might be tough to make the bullet trackable, but it would be a heck of lot easier than constructing nano-space-craft.

First of all its traceable bullets, trackable isn't a word genius.Second of all your super-gun thingy would be in violation of rule number one, the "spirit of the N-Prize" clause.And youve stooped low enough to rant about wether its an M or a N??That shows your just here to spread your bad vibes man, take your negativity elsewhere.

edit:Oh and I am not saying I am GOING to launch a spacecraft using Krogers hydrogen peroxide, i merely said I am going to TRY.Why does it even bother you if someone wants to give something a shot...even if its difficult??
 
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  • #56
Who are these "top scientific professor's" you speak of?
 
  • #57
Iyafrady said:
First of all its traceable bullets, trackable isn't a word genius.And youve stooped low enough to rant about wether its an M or a N??That shows your just here to spread your bad vibes man, take your negativity elsewhere.

edit:Oh and I am not saying I am GOING to launch a spacecraft using Krogers hydrogen peroxide, i merely said I am going to TRY.Why does it even bother you if someone wants to give something a shot...even if its difficult??
Since you are supposedly required to "track" the satellite for 9+ passes, perhaps you ought to pay some attention. I don't care where you get your hydrogen. I could get some at the local Rite-Aid. You have been given a LOT of leeway by the people who run this forum, and I must say that I'm more than a bit disappointed not to see a line through your name already.

Ain't no science happening here!
 
  • #58
Cyrus said:
Who are these "top scientific professor's" you speak of?

The competition was launched in 2008 by Cambridge professor Dr.Paul H. Dear, and is intended specifically to spur amateur involvement in spaceflight.
 
  • #59
Iyafrady said:
The competition was launched in 2008 by Cambridge professor Dr.Paul H. Dear, and is intended specifically to spur amateur involvement in spaceflight.

I'm not finding him on the cabridge website using google.

Edit: I did find him, but under biology.
 
  • #60
Cyrus said:
I'm not finding him on the cabridge website using google.

Edit: I did find him, but under biology.

Yea he is a biology guy but he's also an amateur rocketeer
 
  • #61
Iyafrady said:
Yea he is a biology guy but he's also an amateur rocketeer

So then he isn't a "top scientist" in terms of aerodynamics. Is it even legal to put something into orbit?
 
  • #62
This is a video of the south african team's test launch.

vulcan.jpg

http://www.youtube.com/watch?v=FKIXouBIyyI&feature=channel_page
 
  • #63
turbo-1 said:
and it is possible (if you have budgeted for the lift-mass of the oxidizer) to use hydrogen peroxide for attitude control.

Minor correction, monopropellant hydrogen peroxide is not used as an oxidizer (no redox reaction) - it is rather a catalyzed decomposition, which probably involves radicals (unpaired valence electrons).

H2O2 -> H2O + 1/2O2
 
  • #64
Instead of building this thing like a bunch of yahoos, has anyone sat down and did some actual orbital calculations to make sure you all are not wasting your time chasing a pipe dream?
 
  • #65
Cyrus said:
Instead of building this thing like a bunch of yahoos, has anyone sat down and did some actual orbital calculations to make sure you all are not wasting your time chasing a pipe dream?

Of course we plan to do orbital and gravitational analysis but unfortunately Greg (one of the main developers) got grounded for a couple weeks so he can't use his computer, so that part has to be put on hold.
 
  • #66
Iyafrady said:
Of course we plan to do orbital and gravitational analysis but unfortunately Greg (one of the main developers) got grounded for a couple weeks so he can't use his computer, so that part has to be put on hold.

He got grounded? How old are you guys...really. It's ok if you guys are in high school.
 
  • #67
Cyrus said:
Instead of building this thing like a bunch of yahoos, has anyone sat down and did some actual orbital calculations to make sure you all are not wasting your time chasing a pipe dream?

Well, from 0th-order theory there is no issue, e.g., the rocket equation is invariant under scaling of the rocket. If you could shrink a Delta rocket uniformly by five orders of magnitude, it would still have enough propellant to go wherever a full-size Delta could go.

But then I don't think you can shrink a Delta rocket by five orders of magnitude. I'll defer to you engineers to explain exactly why.
 
  • #68
wolram said:
So the girl reaper was your fault?

I always assumed a graveling in space knocked that toilet seat loose.:biggrin:

That was a great show.
 
  • #69
Team Prometheus
 
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  • #70
signerror said:
Well, from abstract theory there is no issue, e.g., the rocket equation is invariant under scaling of the rocket. If you could shrink a Delta rocket uniformly by five orders of magnitude, nothing would change: it would still have enough propellant to go wherever a full-size Delta could go.

But then I don't think you can shrink a Delta rocket by five orders of magnitude. I'll defer to you engineers to explain exactly why.

I don't follow. An Estees model rock is shrunk down, and it aint going into space.
 
  • #71
Cyrus said:
I don't follow. An Estees model rock is shrunk down, and it aint going into space.

Well it's not simply an scaled-down Delta rocket, is it? The design is (I assume) completely different: it is solid fuel, it is not staged, it probably has a much higher rocket mass/propellant mass ratio, and so forth.

At the 0th-order theory, simply dealing with conservation of energy/momentum, there is no scaling behavior in this equation:

http://en.wikipedia.org/wiki/Tsiolkovsky_rocket_equation

The question is, where does scaling come in? I'm not an engineer, I have no idea. My guesses are it's a structural mechanics issue, or a stability issue involving moments of inertia, or fluid mechanics in the rocket engine, or heat dissipation, or something else that is not scale-invariant.

If you made a perfect scale-model of a Delta that was one inch tall, it would accelerate to orbital speeds. It's the premise that's bad: you can't scale a rocket down to an inch. The walls would be thinner than paper, and it would collapse onto itself.
 
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  • #72
signerror said:
Well it's not simply an scaled-down Delta rocket, is it? The design is (I assume) completely different: it is solid fuel, it is not staged, it probably has a much higher rocket mass/propellant mass ratio, and so forth.

I see. I thought you meant only a geometric scaling. You also meant the bold.

At the 0th-order theory, simply dealing with conservation of energy/momentum, there is no scaling behavior in this equation:

There is scaling effects with drag, which is a huge source of power loss.
 
  • #73
Cyrus said:
There is scaling effects with drag, which is a huge source of power loss.

Yeah, but the thread is about rockets launched from high-altitude balloons, so that doesn't count.
 
  • #74
You'll all be jealous to hear that I am a contestant for the D-Pants challenge-

http://www.truveo.com/DPants/id/3889191887
 
  • #75
Cyrus said:
So then he isn't a "top scientist" in terms of aerodynamics. Is it even legal to put something into orbit?

well first I need FAA clearance to fly anything bigger than 6kg of payload but its not that hard to get for small rockets.If its too much of a hassle the rules state that the organizers won't check wether regulations have been followed so.

Anyway there are currently two ways I have an idea of confirming that the satellite has indeed reached the 100km altitude:

1 way) a long-range transceiver (currently I found one that works for 90 km! and costs as lil as $120) that transmits data with pictures from microcontroller

2 way) the thing enters the atmosphere burns up some of its components, data flash disk survives the descent (after parachute opens) and a small radiosonde turns on telling of its location...

the problem in both ways is power consumption needs...
 
  • #76
Cyrus said:
Instead of building this thing like a bunch of yahoos, has anyone sat down and did some actual orbital calculations to make sure you all are not wasting your time chasing a pipe dream?

Building a rocket without calculations is more like "pipe bomb" than "pipe dream".
 
  • #77
Iyafrady said:
well first I need FAA clearance to fly anything bigger than 6kg of payload but its not that hard to get for small rockets.If its too much of a hassle the rules state that the organizers won't check wether regulations have been followed so.

Anyway there are currently two ways I have an idea of confirming that the satellite has indeed reached the 100km altitude:

1 way) a long-range transceiver (currently I found one that works for 90 km! and costs as lil as $120) that transmits data with pictures from microcontroller

2 way) the thing enters the atmosphere burns up some of its components, data flash disk survives the descent (after parachute opens) and a small radiosonde turns on telling of its location...

the problem in both ways is power consumption needs...

Im pretty sure the FAA only covers the united states. You might want to think harder about what I asked.

Second, I would worry about calculating how much energy you will need before worrying about pie in the sky stuff like long-range tranceivers.
 
  • #78
Dear Iyafrady,
The last time you launched a satellite it crashed in my pond and startled the frogs.I wish you the best of luck with your next attempt but please aim it somewhere else.
 
  • #79
Here's the altitude record for an unmanned gas balloon.
wiki said:
In 2002 Japan achieved a new record: an ultra-thin-film balloon named BU60-1 made of polyethylene film 3.4 µm thick with a volume of 60,000 m³ was launched from Sanriku Balloon Center at 6:35 on May 23, 2002. The balloon kept ascending slowly at a speed of 260 m per minute and successfully reached the altitude of 53.0 km (174,000 ft), establishing a new world record for the first time in 30 years.
http://en.wikipedia.org/wiki/Flight_altitude_record"
Hot air, of course, is a different matter.
You will need a considerable rocket to make the remaining 47 km. This rocket would be payload on the balloon. I assume that any payload would have reduced the altitude acheivable by the balloon and that a rocket that could rise 47 km would prevent the balloon from acheiving the 53 km that it did. I also assume that the balloon alone cost more than $3500, or £999.99. As you go higher, the atmosphere becomes less dense which is good for the rocket, but bad for the balloon. It can't go higher without bursting. I assume that's what happened to the Japanese balloon since that's the easiest way to insure that you have risen as high as possible. It would be advisable to fire off the rocket before the burst since it would be difficult to make sure the rocket was aimed upward after the burst. But then you would take the chance of losing some of the altitude that the balloon could have given you.
 
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  • #80
Iyafrady said:
Team Prometheus


So this is infact for the N-Prize and not for an M-Prize?
Both of the videos you have posted have been labeled for the N-Prize.
Yet your e-mail specifies M-Prize. Do you know what that's all about?
 
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  • #81
Iyafrady said:
Of course we plan to do orbital and gravitational analysis but unfortunately Greg (one of the main developers) got grounded for a couple weeks so he can't use his computer, so that part has to be put on hold.

mwahahahahaa :smile: I was just imagining NASA having those sorts of problems. "Sorry boss, but we have to put the launch back a week 'cos little jimmy is not allowed to come out and play."

hahahahaa



hahahahaha


haha... ha...


*sigh*
 
  • #82
jimmysnyder said:
Here's the altitude record for an unmanned gas balloon.

http://en.wikipedia.org/wiki/Flight_altitude_record"
Hot air, of course, is a different matter.
You will need a considerable rocket to make the remaining 47 km. This rocket would be payload on the balloon. I assume that any payload would have reduced the altitude acheivable by the balloon and that a rocket that could rise 47 km would prevent the balloon from acheiving the 53 km that it did. I also assume that the balloon alone cost more than $3500, or £999.99. As you go higher, the atmosphere becomes less dense which is good for the rocket, but bad for the balloon. It can't go higher without bursting. I assume that's what happened to the Japanese balloon since that's the easiest way to insure that you have risen as high as possible. It would be advisable to fire off the rocket before the burst since it would be difficult to make sure the rocket was aimed upward after the burst. But then you would take the chance of losing some of the altitude that the balloon could have given you.

US Bureau of Mines - http://minerals.usgs.gov/minerals/pubs/commodity/helium/heliumcs06.pdf
The estimated price range for private industry’s Grade-A gaseous helium was about $2.42 to $2.63 per cubic meter ($67 to $73 per thousand cubic feet), with some producers posting surcharges to this price.
At 60,000 m³, the cost would be $120,000 for the He, if one could get it for $2/m³. But price may be higher.

As for the rocket, one needs to size it to see how high it would get with various sizes of balloon.

This may be dated, and it needs to be verified independently. One could contact FMC Chemicals.
http://www.astronautix.com/props/h2o2udmh.htm
Dilute aqueous hydrogen peroxide is concentrated to about 90 per cent by conventional distillation. Higher-strength solutions are prepared by fractional crystallisation of 90 per cent feed stock. Estimated United States production for 1959 was 50,000 tonnes based upon 100 per cent hydrogen peroxide. In large quantities, 95 per cent hydrogen peroxide then cost approximately $1.00 per kg. In small drum lots, 98 per cent solutions cost $ 2.00 per kg. Density varies: 1.44 g/cc for 100% H2O2, 1.43 for 98%, 2.42 for 96%, 1.33 for 75%.

One also needs to calculate the kJ/kg of the propellant. The article also implies a bipropellant H2O2/Unsymmetrical Dimethylhydrazine ((CH3)2NNH2), as opposed to using peroxide as a monopropellant.
This might be useful - http://www.h2o2.com/intro/properties.html


Also launch eastward, with an optimal angle toward the south or SE.
 
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  • #83
Vanadium 50 said:
Building a rocket without calculations is more like "pipe bomb" than "pipe dream".
90% hydrogen peroxide is a very strong oxidizer, and if it comes in contact with something flammable (like something as innocuous as a greasy hand-print) and starts to dissociate, the resulting heat will cause oxygen to gas off more rapidly, then boom! Because it is so hazardous, I would expect that there are permitting requirements for its purchase, storage, and use. Certainly, the UPS man isn't going to drop off the shipment. There are "chain of custody" requirements for hazardous materials. Expect shipping costs for small amounts to far exceed the cost of purchase. Also, once the kids blow up a garage, the insurance company will have every right to refuse to pay damages and then drop any related coverages.
 
  • #84
Here is another issue you will have to deal with.
For a coasting, non-propelled satellite, the lowest circular orbit with a lifetime of several hours is around 85-90 nautical miles (157-167 km). The later Apollo missions used an Earth parking orbit of about 93 nautical miles (172 km).
http://www.bautforum.com/space-astronomy-questions-answers/66070-minimum-orbital-altitude.html"
If the above is correct, then it may be that an orbit at 100 km altitude is more difficult to attain than an orbit at 150 km. But then the rocket needs to be heavier yet and will further depress the maximum height of the balloon that carries it.
 
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  • #85
signerror said:
If you could shrink a Delta rocket uniformly by five orders of magnitude, it would still have enough propellant to go wherever a full-size Delta could go.

But then I don't think you can shrink a Delta rocket by five orders of magnitude. I'll defer to you engineers to explain exactly why.
Take it from an engineer, it can be done. Last night, challenged by what Iyafrady is doing, I decided to compete myself. I asked my wife for $3500 and started building. The Delta IV is a mighty rocket 77 meters tall and capable of a top speed of 25000 miles/hour in the flats. It costs $140,000,000 to launch. In order to meet the cost requirement, I had to scale it down by a factor of 1/40000. And I succeeded. You need a microscope to see the fuel lines, but the thing is an exact replica at a height of .075 inch. Unfortunately, top speed is .62 mph, still short of what I require.
 
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  • #86
turbo-1 said:
90% hydrogen peroxide is a very strong oxidizer, and if it comes in contact with something flammable (like something as innocuous as a greasy hand-print) and starts to dissociate, the resulting heat will cause oxygen to gas off more rapidly, then boom! Because it is so hazardous, I would expect that there are permitting requirements for its purchase, storage, and use. Certainly, the UPS man isn't going to drop off the shipment. There are "chain of custody" requirements for hazardous materials. Expect shipping costs for small amounts to far exceed the cost of purchase. Also, once the kids blow up a garage, the insurance company will have every right to refuse to pay damages and then drop any related coverages.

Were going to get the hydrogen peroxide from Walgreens.
 
  • #87
Iyafrady said:
Were going to get the hydrogen peroxide from Walgreens.
You mean this 3% stuff?
http://www.walgreens.com/store/productlist.jsp?CATID=302248"
 
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  • #88
hypatia said:
Am I the next contestant for the Flight is Right? Hypatia, come on down !

:smile::smile::smile:

The popularity and content of this thread (actual debate concerning H2O2 feasibility as fuel) disturbs me however... wasn't "The Astronaut Farmer" a bad enough movie already, without a reason to remake it?
 
  • #89
Iyafrady said:
Were going to get the hydrogen peroxide from Walgreens.
I presume that is for the first aid kit. :biggrin:
 
  • #90
That stuff women use on their hair sends me into orbit.
 
  • #91
Iyafrady said:
Were going to get the hydrogen peroxide from Walgreens.

They don't sell 90% H2O2. They sell 3%, which is utterly useless as a propellant.
 
  • #92
jimmysnyder said:
You mean this 3% stuff?
http://www.walgreens.com/store/productlist.jsp?CATID=302248"

I thought it was more concentrated than 3%.I just found out i can buy a drum of 50% hydrogen peroxide for 7.00 pesos per kg.That is $0.33 per lb!..The chemistry guys here said they can easily distill it to 90% concentration.Problem solved.
 
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  • #93
jimmysnyder said:
Take it from an engineer, it can be done. Last night, challenged by what Iyafrady is doing, I decided to compete myself. I asked my wife for $3500 and started building. The Delta IV is a mighty rocket 77 meters tall and capable of a top speed of 25000 miles/hour in the flats. It costs $140,000,000 to launch. In order to meet the cost requirement, I had to scale it down by a factor of 1/40000. And I succeeded. You need a microscope to see the fuel lines, but the thing is an exact replica at a height of .075 inch. Unfortunately, top speed is .62 mph, still short of what I require.

Your dimensions are all wrong. Your linear dimensions would fall by the cube root of 40,000, yielding a 52cm rocket; and your speed in a vacuum would remain unchanged (see above comments).
 
  • #94
Iyafrady said:
I thought it was more concentrated than 3%.I just found out i can buy a drum of 50% hydrogen peroxide for 7.00 pesos per kg.That is $0.33 per lb!..The chemistry guys here said they can easily distill it to 90% concentration.Problem solved.

Oh lord.
 
  • #95
turbo-1 said:
90% hydrogen peroxide is a very strong oxidizer, and if it comes in contact with something flammable (like something as innocuous as a greasy hand-print) and starts to dissociate, the resulting heat will cause oxygen to gas off more rapidly, then boom! Because it is so hazardous, I would expect that there are permitting requirements for its purchase, storage, and use. Certainly, the UPS man isn't going to drop off the shipment. There are "chain of custody" requirements for hazardous materials. Expect shipping costs for small amounts to far exceed the cost of purchase. Also, once the kids blow up a garage, the insurance company will have every right to refuse to pay damages and then drop any related coverages.

Actually hydrogen peroxide is one of the safest propellants available.Its non volatile, non explosive, non inflammable and non toxic product.Its pretty much oxygenated water dude.The most dangerous thing about it is a little bit irritating to the eyes.Its stability also increases with concentration, so its safer to store and transport than gasoline.
 
  • #96
Iyafrady said:
I thought it was more concentrated than 3%.I just found out i can buy a drum of 50% hydrogen peroxide for 7.00 pesos per kg.That is $0.33 per lb!..The chemistry guys here said they can easily distill it to 90% concentration.Problem solved.
But can they distill it to 500%?

Enthalpy of decomposition of peroxide is about 3kJ/g or 3MJ/kg.

Typical orbital velocity for a LEO is about 8km/sec. So an object in LEO needs an increase in specific KE of about 30MJ/kg (ignoring drag).

Without actually doing the integral, this seems to say that 100% peroxide doesn't have enough chemical energy in it to propel nothing more than its own weight into LEO, operating at 100% efficiency - forget about carrying a rocket along.
 
  • #97
Iyafrady said:
Actually hydrogen peroxide is one of the safest propellants available.Its non volatile, non explosive, non inflammable and non toxic product.Its pretty much oxygenated water dude.The most dangerous thing about it is a little bit irritating to the eyes.Its stability also increases with concentration, so its safer to store and transport than gasoline.

You're completely wrong. It is extremely corrosive and will eat right through skin. You are confusing it with extremely dilute, 3% pharmacy-grade peroxide (which is mostly water).
 
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  • #98
Gokul43201 said:
But can they distill it to 500%?

Enthalpy of decomposition of peroxide is about 3kJ/g or 3MJ/kg.

Typical orbital velocity for a LEO is about 8km/sec. So an object in LEO needs an increase in specific KE of about 30MJ/kg (ignoring drag).

Without actually doing the integral, this seems to say that 100% peroxide doesn't have enough chemical energy in it to propel nothing more than its own weight into LEO, operating at 100% efficiency - forget about carrying a rocket along.

This is invalid: you're forgetting that propellant is removed throughout the burn time of a rocket - the mass reaching LEO is much smaller than what is launched.
 
  • #99
signerror said:
Your completely wrong. It is extremely corrosive and will eat right through skin. You are confusing it with extremely dilute, 3% pharmacy-grade peroxide (which is mostly water).

Thats why were going to wear protective goggles and gloves.But its not flammable like gasoline!
 
  • #100
Iyafrady said:
Actually hydrogen peroxide is one of the safest propellants available.Its non volatile, non explosive, non inflammable and non toxic product.Its pretty much oxygenated water dude.The most dangerous thing about it is a little bit irritating to the eyes.Its stability also increases with concentration, so its safer to store and transport than gasoline.
You are dangerously misinformed and there may be gullible people reading this thread that could be killed or injured trying some of this stuff. Hydrogen peroxide is NOT a fuel. It is used as a propellant due to its ability to expand very rapidly. That said, concentrated hydrogen peroxide is very dangerous because it is has extra oxygen that can become un-bound easily and can spontaneously ignite and/or explode when it comes in contact with oxidizable materials (fuels) or dusts or metals or the salts of those metals. I hope you're just playing games and fantasizing about making such a rocket, because you don't have the requisite knowledge to handle this stuff safely.

http://cameochemicals.noaa.gov/chemical/19279
Reactivity Profile
HYDROGEN PEROXIDE, AQUEOUS SOLUTION, STABILIZED, WITH MORE THAN 60% HYDROGEN PEROXIDE is a powerful oxidizing agent. Will react or decompose violently and exothermically with readily oxidizable materials or alkaline substances. May decompose violently in contact with iron, copper, chromium, and most other metals or their salts, which act as catalysts for this reaction, and with ordinary dust (which frequently contain rust, also a catalyst for this reaction). Stabilization operates against such reactions, but does not eliminate their possibility. Contact with combustible materials may result in their spontaneous ignition. Solutions containing over 30% hydrogen peroxide can detonate when mixed with organic solvents (such as acetone, ethanol, glycerol); the violence of the explosion increases with increasing concentration of the hydrogen peroxide. Concentration of solutions of hydrogen peroxide under vacuum led to violent explosions when the concentration was sufficiently high (>90%) [Bretherick 2nd ed., 1979]. Mixtures of aqueous hydrogen peroxide with 1-phenyl-2-methyl propyl alcohol tend to explode if acidified with 70% sulfuric acid [Chem. Eng. News 45(43):73(1967); J, Org. Chem. 28:1893(1963)]. Hydrogen selenide and hydrogen peroxide undergo a very rapid reaction [Mellor 1:941(1946-1947)].
 
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