Ideal gas law mechanical work problem

AI Thread Summary
The discussion focuses on calculating the mechanical work done by a gas during a thermodynamic process, specifically between volumes of 2 and 4 liters. The initial solution provided was 505 J, but the user initially calculated 306 J, leading to confusion about the integration process. After reviewing the calculations, it was determined that the gradient of the curve and unit conversions from atm to Pa were crucial for accuracy. The user corrected their approach, realizing the importance of using the correct terms in the integral. Ultimately, the assessment of the calculations was confirmed as correct, leading to a resolution of the problem.
DrOnline
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Homework Statement


4g70SY0.jpg


Calculate the gas' mechanical work on its environment for the thermodynamic process path IF.

Solution says: 505 J


Homework Equations



W=\int_i^f p,dv

i = Vi, initial volume
f = Vf, final volume


The Attempt at a Solution



My approach is to find a function for p(v) between 2 and 4 liters.

p(v) = 709275 - \frac{3}{2} * 101325 V (Pa)

And then integrate it from 2 to 4 liters, which is 0.002m3 to 0.004m3

Problem is, I get:
rKpGaeu.jpg


Which is way off. I should get 505 J..

I'm stumped. What am I doing wrong?
 
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where did you get your 709275 number?

Anyway, I make it about 306 J.
 
Oh, I should have stated that. I extended the IF line to where it intersects with the Y-axis, which is 7 atm.

7 * 101325 Pa = 709275 Pa.

You got 306 J... it should be 505, unless the document is wrong.
 
DrOnline said:
Oh, I should have stated that. I extended the IF line to where it intersects with the Y-axis, which is 7 atm.

7 * 101325 Pa = 709275 Pa.

You got 306 J... it should be 505, unless the document is wrong.

The first time I just calculated area = 1/2 bh and got 306.

This time I did the integration and got ~ 518. And I found your mistake - in your 2nd term under the integral you divided by 2 instead of 0.002.

Still don't know why 1/2 bh didn't work! :frown:
 
Thank you for your help. Gonna ask the professor about it, he made the task after all.

The second term is -(3*2) because that is the gradient of the curve. That should be correct.
 
DrOnline said:
Thank you for your help. Gonna ask the professor about it, he made the task after all.

The second term is -(3*2) because that is the gradient of the curve. That should be correct.

It's not correct. The second term should be -(3/2) * 101,325/0.001 V.
I wouldn't go to your professor 'till we agree on this.
 
rude man said:
It's not correct. The second term should be -(3/2) * 101,325/0.001 V.
I wouldn't go to your professor 'till we agree on this.

My God, that seemed to do the trick.

DcgSep2.jpg


This seems right to me.

I gather since I converted from atm to Pa, and integrated using m3 instead of liters, I also should have taken that into account for the gradient.

Is that assessment correct?
 
DrOnline said:
My God, that seemed to do the trick.

DcgSep2.jpg


This seems right to me.

I gather since I converted from atm to Pa, and integrated using m3 instead of liters, I also should have taken that into account for the gradient.

Is that assessment correct?

That assessment is fully correct! :smile:
 
Thank you very much!
 
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