Jj coupling scheme and electronic configuration

In summary, the possible terms for the given electronic configurations (considering jj coupling scheme) are (1/2,1/2)0 and (1/2,1/2)1 for 1s2, (1/2,1/2)0 and (1/2,1/2)1 for 1s2s, (1/2,1,1,1,3/2,3/2)0, (1/2,1,1,1,3/2,3/2)1, (1/2,1,1,1,3/2,3/2)2, and (1/2,1,1,1
  • #1
vst98
51
0

Homework Statement


Write all possible terms (n1 j1, n2 j2, …) J
for these electronic configurations (considering jj coupling scheme):
1s2
1s2s
1s22s22p
1s22s22p5

The Attempt at a Solution



1s2
I have two electrons in the s sub-shell,
since |l-s|<=j<=l+s then j1=1/2 and j2=1/2.
This gives possible J values of J=0,1 and the terms are

(1/2,1/2)0 (1/2,1/2)1


1s2s
one electron in 1s and one in 2s.
Again using a rule |l-s|<=j<=l+s gives j1=j2=1/2 for both electrons.
j1 and j2 can couple together go give total J=0,1 so the terms are again

(1/2,1/2)0 (1/2,1/2)1


So far I'm not sure that this is right, do I have to do this calculations with all electrons
or can I ignore completely filled shells ? But what about 1s2s then ? Also is my designation
of these terms like (j1,j2)J correct ?
 
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  • #2
1s22s22pOne electron in 1s, two in 2s and two in 2p.Again using a rule |l-s|<=j<=l+s gives j1=1/2, j2,j3,j4=1 for all electrons in 2s and j5,j6=3/2 for electrons in 2p.These six can couple together to give total J=0,1,2,3 so the terms are(1/2,1,1,1,3/2,3/2)0 (1/2,1,1,1,3/2,3/2)1 (1/2,1,1,1,3/2,3/2)2 (1/2,1,1,1,3/2,3/2)31s22s22p5One electron in 1s, two in 2s, two in 2p and one in 5s.Again using a rule |l-s|<=j<=l+s gives j1=1/2, j2,j3,j4=1 for all electrons in 2s and j5,j6=3/2 for electrons in 2p and j7=1/2 for electron in 5s.These seven can couple together to give total J=0,1,2,3,4,5 so the terms are(1/2,1,1,1,3/2,3/2,1/2)0 (1/2,1,1,1,3/2,3/2,1/2)1 (1/2,1,1,1,3/2,3/2,1/2)2 (1/2,1,1,1,3/2,3/2,1/2)3 (1/2,1,1,1,3/2,3/2,1/2)4 (1/2,1,1,1,3/2,3/2,1/2)5
 

Related to Jj coupling scheme and electronic configuration

What is the Jj coupling scheme?

The Jj coupling scheme is a method used to describe the electronic configuration of atoms with multiple electrons. It takes into account the interactions between the electrons and considers their spin and orbital angular momentum.

How does the Jj coupling scheme differ from other coupling schemes?

The Jj coupling scheme differs from other coupling schemes, such as LS coupling and jj coupling, in that it considers both spin and orbital angular momentum, whereas the other schemes only consider one or the other.

What is the significance of the Jj coupling scheme in atomic physics?

The Jj coupling scheme is significant in atomic physics because it provides a more accurate description of the electronic configuration of atoms with multiple electrons. It also allows for a better understanding of the energy levels and electron transitions in these atoms.

How is the Jj coupling scheme used in spectroscopy?

The Jj coupling scheme is used in spectroscopy to interpret the spectral lines of atoms with multiple electrons. It helps to identify and analyze the energy levels and transitions of these atoms, providing valuable information for studying their properties and behaviors.

Can the Jj coupling scheme be applied to all atoms?

Yes, the Jj coupling scheme can be applied to all atoms with multiple electrons. However, it is most commonly used for atoms with heavy elements or atoms with high spin states.

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