Kinetic energy of electron & energy states

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Homework Help Overview

The discussion revolves around the kinetic energy of an electron and its energy states, specifically focusing on deriving the energy of an electron in its lowest energy state using the kinetic energy relationship. The problem involves concepts from quantum mechanics and wavefunctions.

Discussion Character

  • Exploratory, Conceptual clarification, Mathematical reasoning, Problem interpretation

Approaches and Questions Raised

  • Participants discuss the relationship between kinetic energy and the electron's energy state, with one participant expressing difficulty in starting the problem. Questions are raised about the meaning of L and the boundary conditions for the electron's motion within a box.

Discussion Status

Some participants have provided insights into the problem setup, including the interpretation of L as the side length of a box and the implications of boundary conditions. Suggestions for approaches include writing down the Schrödinger equation or considering the electron's wavefunction and deBroglie wavelength.

Contextual Notes

The problem lacks explicit boundary conditions, which are relevant for determining the electron's behavior in the box. The context suggests that the electron is treated as a particle in a one-dimensional box, with implications for its wavefunction.

Kognito
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Homework Statement



Use the relationship kinetic energy E = p^2/2m to show that the energy [itex]E_{0}[/itex] of an electron of mass m in its lowest energy state is given by [itex]E_{0}[/itex] = h^2/8mL^2


Homework Equations



E = p^2/2m

[itex]E_{0}[/itex] = h^2/8mL^2


The Attempt at a Solution



I've stared at this for far too long, googled it to death as well as checked through all my course materials and I can't seem to get started with it. Any ideas at all would be welcome.

Thank you in advance,
Kognito
 
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What is L here? Is the electron in a 3d box and L is the side length? Does the problem say what boundary conditions it wants you to apply at the box edges?
 
My apologies, I missed that off the end of the sentence (too busy messing with equation formatting controls).

But yes, L represents a box within which the electron resides. The question doesn't specifically mention boundary conditions though the previous part of the question said to draw the electron in its lowest energy state, able to move freely along the length of the box, as represented by a standing wave.
 
There's two things you can do... one is write down the Schrödinger equation and then solve it.

The other is to say that the electron's wavefunction has to have nodes at the box edges, so write down an expression for its deBroglie wavelength and apply the appropriate constraints to it.
 

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