Linus Pauling's General Chemistry

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SUMMARY

The discussion focuses on the crystalline structures presented in Linus Pauling's "General Chemistry," specifically the face-centered cubic structure of copper and the body-centered cubic structure of iron. Copper's unit cell coordinates are identified as 0,0,0; 0,1/2,1/2; 1/2,0,1/2; and 1/2,1/2,0, while iron's unit cell coordinates are 0,0,0 and 1/2,1/2,1/2. Participants express difficulty in visualizing these structures, particularly when interpreting stereoscopic images. The discussion references the Dover republication of the text and additional resources for clarity.

PREREQUISITES
  • Understanding of crystalline structures in solid-state chemistry
  • Familiarity with unit cell concepts in crystallography
  • Knowledge of stereoscopic imaging techniques
  • Basic principles of atomic coordination in crystal lattices
NEXT STEPS
  • Explore the differences between face-centered and body-centered cubic structures
  • Study the concept of atomic coordination numbers in crystal structures
  • Learn about stereoscopic imaging and its applications in chemistry
  • Review additional resources on solid-state chemistry and crystallography
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Chemistry students, educators, and professionals interested in solid-state chemistry, crystallography, and the visualization of atomic structures.

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Is anyone able to comment on the crystalline structures in the second chapter? Copper's cubic unit of structure is described as a face-centered cubic arrangement with atoms at coordinates 0,0,0; 0,1/2,1/2; 1/2,0,1/2; 1/2,1/2,0.

The iron cubic unit of structure is described as a body-centered arrangement. There are two atoms in the unit at coordinates 0,0,0 and 1/2, 1/2, 1/2.

Also, what am I supposed to gather from the stereoscopic image? I'm having trouble imagining this spatially even with the diagrams.

Most of the above is a direct quote from p25 in the Dover republication of General Chemistry.
 
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Thanks for the response. The difference between the face-centered and body-centered cubic units were troubling me. I referenced my general chemistry text for a more elementary explanation than Pauling's.
 

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