Pressure change with constant volume

AI Thread Summary
The discussion revolves around a thermodynamics problem involving two moles of a gas undergoing an isochoric process where the pressure is doubled from 2 Atm to 4 Atm. Participants are trying to determine the change in temperature (ΔT), the work required, and the change in internal energy of the gas. The first law of thermodynamics is applied, noting that under constant volume, the entire energy spent on heating translates into internal energy change. There is uncertainty about whether the ideal gas law can be assumed for solving the problem, with requests for hints on relating temperature change to pressure without this assumption. The conversation highlights the complexities of thermodynamic equations in constant volume scenarios.
SadStudent
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Homework Statement


Given two moles of some gas with two atoms per molecule which has energy U=aK_{B}T.
Assume the initial pressure is P_{i}= 2 Atm and the initial volume is P_{i}= 0.001\ m^{3}.
Now we heat it in an isochoric process to 2P_{i}.

What would be \Delta T?
What would be the work required to do that?
What would be the change in the gas particles' internal energy?

Homework Equations


U=aK_{B}T
dU=PdS-TdV

The Attempt at a Solution


Well using the first law of thermodynamics, I got that under constant volume dV=0 so \frac{dQ}{dT}=\frac{\partial U}{\partial T} so the entire energy that we spent on heating would be transferred into the gas.
What's a tricky to me is to formulate the change in temperature as a function of pressure because dV=0 so I'd really welcome a hint.

Thanks!
 
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SadStudent said:

Homework Equations



dU=PdS-TdV

Oops, check that.

What's a tricky to me is to formulate the change in temperature as a function of pressure because dV=0 so I'd really welcome a hint.

Can you assume the gas obeys the ideal gas law?
 
TSny said:
Oops, check that.Can you assume the gas obeys the ideal gas law?

And yes of course it was a typo :) it's supposed to be dU=TdS-PdV

I'm really not sure whether I can, is there a way of solving this without this assumption?
 
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