Specific Heat Problem, not getting the correct answer

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Homework Help Overview

The discussion revolves around a specific heat problem involving a copper pot, water, and a block of iron, focusing on the calculation of the final temperature of the system after thermal equilibrium is reached. The participants are examining the principles of heat transfer and specific heat capacities in a closed system.

Discussion Character

  • Conceptual clarification, Mathematical reasoning, Assumption checking

Approaches and Questions Raised

  • Participants discuss the setup of the heat transfer equation, questioning the signs used for temperature changes and the correct formulation of the heat balance. There is an exploration of how to represent the heat gained and lost by different materials.

Discussion Status

There is ongoing clarification regarding the correct formulation of the heat transfer equation. Some participants suggest adjustments to the signs in the equation and emphasize the importance of correctly identifying the temperature changes for each material involved. The conversation indicates a productive exploration of the problem without reaching a consensus on the final answer.

Contextual Notes

Participants are working under the assumption that there is no heat loss to the surroundings, and they are addressing potential misinterpretations of the problem setup and the equations involved.

HRubss
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Homework Statement


A copper pot with a mass of 0.500 kg contains 0.170 kg
of water, and both are at a temperature of 20.0°C. A 0.250-kg
block of iron at 85.0°C is dropped into the pot. Find the final temperature
of the system, assuming no heat loss to the surroundings.

Homework Equations


Q = cmΔT
ΣQ = 0

The Attempt at a Solution


Since I know that all these materials will reach thermal equilibrium and that the iron will be the only one losing heat so...

CcoppermcopperΔT + CwatermwaterΔT - CironmironΔT = 0

I expanded all the specific heats, brought the individual heats at initial temperature and then solved for Tfinal. I got...
Tfinal = (CcoppermcopperTinitial+CwatermwaterTinitial-CironmironTinitial) /(Ccoppermcopper+Cwatermwater-Cironmiron)

I converted to Kelvin and got about 10.47°C, the answer should be 27.45°C... I don't understand what I did wrong.
 
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HRubss said:
CcoppermcopperΔT + CwatermwaterΔT - CironmironΔT = 0
You should put a plus sign in front of CironmironΔT and you shouldn't really use the same symbol ΔT to denote two temperature changes in this case. The equation says that the sum of all the heat transfers must be zero as the iron loses heat (negative ΔTiron) and the copper and water gain heat (positive ΔTcopper+water). In other words, the changes in temperature are algebraic quantities, that could be positive or negative.
 
kuruman said:
You should put a plus sign in front of CironmironΔT and you shouldn't really use the same symbol ΔT to denote two temperature changes in this case. The equation says that the sum of all the heat transfers must be zero as the iron loses heat (negative ΔTiron) and the copper and water gain heat (positive ΔTcopper+water). In other words, the changes in temperature are algebraic quantities, that could be positive or negative.

So the equation should be like this?
ΔQ(copper) + ΔQ(water) = - ΔQ(iron)
 
HRubss said:
So the equation should be like this?
ΔQ(copper) + ΔQ(water) = - ΔQ(iron)
Sure, or equivalently:

ΔQ(copper) + ΔQ(water) + ΔQ(iron) = 0

The trick is to get the ΔQ's correct for each term, and that means paying attention to the signs of the temperate changes that apply to each of the ΔQ's (some materials are rising in temperature, gaining heat, while others are lowering in temperature, losing heat).
 
gneill said:
Sure, or equivalently:

ΔQ(copper) + ΔQ(water) + ΔQ(iron) = 0

The trick is to get the ΔQ's correct for each term, and that means paying attention to the signs of the temperate changes that apply to each of the ΔQ's (some materials are rising in temperature, gaining heat, while others are lowering in temperature, losing heat).
So...
Substituting the entire formula:
CMΔT(copper) + CMΔT(water) = -CMΔT(iron)
I know that ΔT of copper and water should be the same and I want to get all the T(final) all on one side:
ΔT(CM(copper) + CM(water)) = -CMT(final, iron) + CMT(initial, iron),
and from here, I split up the ΔT of copper/water and then solve for T final by getting the iron's Tfinal on the other side?
 
Sure, that's the idea.
 
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