Chrisc said:
You seem unwilling, even in principle, to consider the principle of conservation of momentum in an event unless you can simultaneously consider the conservation of heat energy in the same event.
All that matters is that total energy is conserved, it doesn't matter whether there's any heat energy present or not. Weren't you supposed to be discussing the question of whether a given situation is a violation of the dynamical laws? Well, any situation where total energy isn't conserved violates the known dynamical laws and is thus physically impossible according to the known laws of physics.
Chrisc said:
It is true a "single" point mass does not posess heat energy, nor does a "single" molecule, or in principle a single anything. It is the collective distribution of kinetic energy of a "single" entity's constituents that defines the heat energy of the entity as a whole.
But how do you propose to arrive at a collective distribution of kinetic energy if you consider the collision of any two constituents "completely impossible according to the dynamical laws"?
The collision of any two pointlike constituents is not "completely impossible", it's just that the only type of collision between pointlike entities which the dynamical laws allow is one where their kinetic energy is conserved. For any pair of initial velocities for the two particles, it is always possible to find a
unique set of post-collision velocities such that both momentum and kinetic energy are conserved (and this is what is known as an 'elastic collision'). As an example, in your scenario 1A, you had the 2kg mass initially moving at 2 m/s while the 1 kg mass was initially at rest, prior to the collision. Well, if there is no change in heat energy in this collision, then the only possible set of post-collision velocities would be the 2 kg mass moving at 2/3 m/s and the 1 kg mass moving at 8/3 m/s. In this case the total momentum both before and after the collision will be 4 kg*m/s, while the total kinetic energy both before and after the collision will be 4 kg*m^2/s^2. Assuming there is no change in some other form of energy like heat energy, then this is the only set of post-collision velocities which are allowed by the dynamics (if you set up the equations (2 kg)*v1 + (1 kg)*v2 = 4 kg*m/s and (1/2)*(2 kg)*v1^2 + (1/2)*(1 kg)*v2^2 = 4 kg*m^2/s^2, you can solve these equations and see that there are only two possible sets of solutions for v1 and v2, one of which gives the velocities before the collision and one of which gives the velocities after).
Chrisc said:
It seems from this same reasoning you think that the second law of thermodynamics is not observed in the collision of two masses, but only on some greater number of masses.
What do you mean by "two masses" vs. a "greater number of masses"? If we have a collision between two macroscopic balls which are themselves made up of many molecules, would you call this "a greater number of masses"? Are you using the term "two masses" to refer exclusively to something like point masses which are not composed of multiple parts? If so, it's true that there can be no change in
heat energy in the collision between two point masses, and the basic dynamics demand that total energy (and total momentum)
must be conserved in every collision. This doesn't necessarily mean there can be no
change in entropy in the system at all, since the entropy of some combination of velocities for the point masses might be higher than others, although to talk about changes in entropy you have to have some macro-parameters such that there are multiple possible microscopic states (microscopic states means a precise set of values for the position and momentum of each particle) compatible with a single value of the macro-parameter, with the entropy of a given value of the macro-parameter being proportional to the logarithm of the number of possible microscopic states associated with it, and I'm not sure what kind of macro-parameter you could define for a system consisting of only two point particles. I have my doubts that you could define one such that a collision would involve any
change in entropy (though I'm pretty sure you could define one for an isolated system with
three parts, like three particles in a closed universe or two particles in a box).
Chrisc said:
This is not true. A change in the distribution of momentum during the collision of two masses will not display a spontaneous "increase" in the total momentum of the system. i.e. a spontaneous "decrease" in entropy.
You can never have a spontaneous increase or decrease in total momentum, not even in situations where entropy changes. The momentum vector of a composite object made of many molecules or other parts is just the sum of the momentum vectors of all the parts, so a pair of composite object can't balance out a decrease in momentum for the centers of mass of the two objects by an increase in the total momentum of all the parts that make them up. On the other hand, the kinetic energy of the center of mass of a composite object is
not the sum of the kinetic energies of all the parts making it up, so it is possible to have a decrease (or increase) in the sum of the kinetic energies for the two centers of mass be balanced out by an increase (or decrease) in the sum of the kinetic energies of all the parts that make up the larger masses.
Chrisc said:
The system will display either no
change in entropy while conserving the total momentum, or an increase in entropy while conserving the total momentum. Where the latter simply means the total momentum of the system is more evenly distributed between the masses, i.e. the momentum of the system approaches equilibrium.
In order to make this statement well-defined you'd need some parameter which defines how "evenly distributed" the momenta are...I suppose you could use the sum of the
squares of the momentum for each particle, a parameter which decreases as the momentum becomes more evenly distributed, but this would essentially just be the sum of kinetic energies multiplied by a constant.
Chrisc said:
If I had presented an example that had a complete disregard for the laws of conservation I could understand your objections. But I have not.
Do you acknowledge that conservation of energy is one of the "laws of conservation", separate from conservation of momentum. Do you acknowledge that in your scenario, the sum of kinetic energies of the centers of mass of the two objects is different after the collision than it was before? If so, you should agree that unless there is a change in some other form of energy (like heat) in your scenario, then your scenario
does disgregard the "laws of conservation".
Chrisc said:
I have presented a simple two-mass event that considers the principle of conservation of momentum in context of the principle of relativity as a set of frame dependent observations that will both break or violate the second law of thermodynamics and uphold it, depending on the frame of the observer.
If your scenario obeys the laws of conservation, it must involve a change in some other form of energy besides the kinetic energies of the centers-of-mass, like heat. All valid inertial frames will agree on whether the heat increases or decreases after the collision, so there is no disagreement on whether the 2nd law of thermodynamics is upheld or violated. I suppose if we consider a situation where there is no change in heat, like the one I suggested where the post-collision velocities were 2/3 m/s and 8/3 m/s, then for some sufficiently weird choice of macro-parameter one
might be able to show that a collision took the system to a value of the macro-parameter with higher entropy in one frame while it took the system to a value with lower entropy in another frame, though as I said earlier I have my doubts that this is possible for a system with only two parts. But in any case, if one chooses the usual macro-parameters which are normally used to define entropy in thermodynamics, like temperature and pressure, I'm pretty sure an increase in entropy in one inertial frame would mean an increase in every inertial frame.
Chrisc said:
The point I have rephrase and paraphrased numerous times is:
The time symmetry of the "principle" of relativity is broken by the time asymmetry of the second law of thermodynamics.
Where do you get the idea that the principle of relativity requires that the laws of physics be time-symmetric? It doesn't, time-symmetry is a separate postulate. And the apparent asymmetry of the second law is not a violation of time-symmetry, again because it is ultimately just a consequence of the initial conditions of the universe near the Big Bang, not of the laws of physics themselves. The particular arrangement of matter and energy in spacetime can be asymmetric even if the laws of physics are symmetric; as another example, the laws of physics exhibit rotation symmetry meaning there is no preferred direction in space, and this would continue to be true even if we imagine that all of space happened to be filled with some magnetic material that allowed everyone to orient themselves in the same direction using a compass.
Chrisc said:
This arises from the relativity of observation presenting frame dependent dynamics, which shows there is a preferred or privileged frame(one where the observer is initially at rest with the smaller mass) in which one can uphold both the time symmetry of dynamical laws and the time asymmetry of the second law of thermodynamics. It is a preferred or privileged frame "because" the only other frame in the system (initially at rest with the larger mass) will not uphold both but must break either one in order to uphold the other.
Please be explicit about the
change in entropy that you think is happening in different frames in your scenario--are you suggesting that in 1B the entropy has increased beyond what it was in 1A, while in 2B (which is just 1B viewed in a different frame) the entropy has decreased from 2A? If so you're wrong, the only way your scenario could be consistent with the laws of dynamics would be if the heat energy increased after the collision, and it would have to increase in both frames. You're free to pick a different scenario where the sum of kinetic energy for the centers-of-mass is conserved and so there is no need for a change in heat (like my scenario which starts the same as 1A, but after the collision leaves the 2 kg mass moving at 2/3 m/s and the 1 kg mass moving at 8/3 m/s in that frame), but in this case if you want to assert that there's some
change in entropy before and after the collision, you'll have to specify what macro-parameter(s) you're using to define entropy.