There is no problem doing that. However, the volume element is then different: you can calculate it using classical geometry or using the Jacobian of your new coordinate system. If you integrate the old volume element using your new coordinate system, what you are integrating will no longer represent volume.
In particular, recall that the ##r\sin \phi ## factor of the volume element ##r^2 \sin\phi \, dr\, d\theta\, d\phi ## comes about geometrically from the length of the projection of the radial position vector of each point onto the xy-plane in order to get the sweeping radii for the lengths of arc ##d\theta ## and ##d\phi ##. If you are now allowing ##\phi ## to have values above 180°, then ##r\sin \phi ## will be a negative number when ##180^{\circ} < \phi < 360^{\circ}##. We do not want those projection lengths to be negative, so that is not the standard volume element anymore.
To get the correct standard volume, you can use the factor ##r|\sin \phi |## instead, which would result in a volume element of ##r^2 |\sin\phi | \, dr\, d\theta\, d\phi ##. However, I think you can see that this is a bit unwieldy.