What is the total probability of finding a particle in a one-dimensional box

In summary: You may need to use the Laplacian. In summary, the student is trying to solve a problem in chemistry without using calculus, but is unsure of how to proceed. The student is given a few helpful hints, including the suggestion to use the Schrödinger equation and differentiation, to solve the problem.
  • #1
bamboy192
2
0
Hi,
This is my first equation that I need to solve and both my textbook and professor have not shown me how to do it. I'm in chemistry and there isn't a prerequisite for calculus so I was wondering if I could be shown a way to solve this problem without doing calculus but if there isn't a way, the answer will still be beneficial.

Thanks

What is the total probability of finding a particle in a one-dimensional box in level n = 3 between x = 0 and x = L/6?

Homework Equations


Psi = sqrt(2/L)sin(n pi x /L)
 
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  • #2
How is the probability of finding a particle in a region related to the wavefunction of the particle?
 
  • #3
You will probably get some funny looks here about a QM course without calculus. You are not actually forbidden to learn any. You'll have to be smarter to do QM without it than with - but you can do this problem.

You can't without knowing what a sine is and what its graph looks like, what pi and radians are. Maybe that counts as pre-calculus.

Useful to realize until you are more used to it, in a problem like this you are allowed to set L = 1 if you find that simplifies for you. Because L is just a length which is measured in some units and I am going to measure it in units so that it comes to 1. (in some other probs. where real lengths are given you may not have this freedom.)

Then draw a picture of what that function looks like. You can probably then guess the answer.

However the question asks you about probability and you really must know what the relation of your psi is to the probability of finding a particle in a certain space - in this case in a certain length. So do another picture of what that 'probability density' looks like in your problem. Then basically the regularity or symmetry of your pic will give you the answer.

You are going to have to think smart like this for other problems (calculus does some of the thinking for you).
 
  • #4
thanks for the reply, can you show me using calculus because even though the class doesn't require it, I've already taken it so maybe that would be the best approach.
 
  • #5
bamboy192 said:
thanks for the reply, can you show me using calculus because even though the class doesn't require it, I've already taken it so maybe that would be the best approach.

It would be bad if my general comments influenced you to not just solve that problem in the way I indicated, making you think you need to wait till you have studied something else. Just draw those two figs and I hope it will be obvious.

If you have done a bit then you will know the bit of math I suggested you use. Which is almost not calculus though it gets a lot treated in calculus courses and physical applications.

The calculus comes in in getting that equation that the Prof gave you. It is obtained from the 1-dimensional quantum wave equation aka the Schrödinger equation. If you know that equation a bit of calculus you can then verify that it is a solution of the Schrödinger equation in the particular case of Particle in a Box. It is an exercise in differentiation.
 

1. What is a one-dimensional box in the context of particle physics?

A one-dimensional box is an idealized system used in quantum mechanics to model the confinement of a particle within a finite space. It is commonly represented as a one-dimensional line segment with impenetrable walls at either end, creating a "box" in which the particle can move.

2. How is the probability of finding a particle in a one-dimensional box calculated?

The probability of finding a particle in a specific location within a one-dimensional box is determined by solving the Schrödinger equation for the given system. This involves using mathematical techniques such as integration and eigenvalue analysis to find the wave function, which describes the probability amplitude of the particle at different positions.

3. What is the significance of the total probability of finding a particle in a one-dimensional box?

The total probability of finding a particle in a one-dimensional box is a fundamental concept in quantum mechanics that helps us understand the behavior of particles in confined spaces. It tells us the likelihood of the particle being at a certain position, and also helps to define the energy levels and allowed states within the box.

4. Can the total probability of finding a particle in a one-dimensional box ever be greater than 1?

No, the total probability of finding a particle in a one-dimensional box is always equal to 1. This is because the particle must be somewhere within the box, so the sum of the probabilities of finding it at all possible positions must equal 1.

5. How does the size of the box affect the total probability of finding a particle?

The total probability of finding a particle in a one-dimensional box is directly proportional to the size of the box. As the size of the box increases, the probability of finding the particle at any given position decreases, and vice versa. This is because a larger box allows for more possible positions for the particle, resulting in a lower overall probability of finding it at any one location.

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