Which one is reducing and which is oxidising?

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Discussion Overview

The discussion revolves around identifying which half-equation represents oxidation and which represents reduction in electrochemical reactions. Participants explore the use of standard reduction potentials and mnemonic devices related to electron transfer.

Discussion Character

  • Conceptual clarification, Technical explanation, Debate/contested

Main Points Raised

  • Some participants suggest that understanding the flow of electrons is key, noting that losing electrons corresponds to oxidation and gaining electrons corresponds to reduction.
  • One participant emphasizes the use of the standard reduction potentials table to determine the reactions' nature when both half-cells are present.
  • A mnemonic, "OIL RIG," is introduced as a memory aid for remembering the definitions of oxidation and reduction.

Areas of Agreement / Disagreement

Participants express some agreement on the definitions of oxidation and reduction, but there is no consensus on the necessity of using the standard reduction potentials table for determining the reactions in the given half-equations.

Contextual Notes

Some assumptions about the context of the half-equations and their application in electrochemical cells remain unaddressed, and the discussion does not resolve the necessity of the standard reduction potentials table.

Procrastinate
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When a question with two half equations set out like below, how do I tell which one is oxidising and which one is reducing? Do I have to apply the standard reduction potentials table?

Co2+ + 2e- -> CO (s)
Ag+ +e- -> Ag (s)

Thank you.
 
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Procrastinate said:
When a question with two half equations set out like below, how do I tell which one is oxidising and which one is reducing? Do I have to apply the standard reduction potentials table?

Co2+ + 2e- -> CO (s)
Ag+ +e- -> Ag (s)

Thank you.

Remember, lose electrons oxidized, gain electrons reduced
 
gabriels-horn said:
Remember, lose electrons oxidized, gain electrons reduced

And as a memory aid:

OIL. RIG

Oxidation Is Loss. Reduction Is Gain (of electrons)
 
Procrastinate said:
Do I have to apply the standard reduction potentials table?

Assuming you were asked to say what will happen if both half cells are present - yes.

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