Work done by a gas with only pressure and volume

AI Thread Summary
An ideal diatomic gas undergoes adiabatic compression from an initial pressure of 1.20 atm and volume of 0.200 m^3 to a final pressure of 2.40 atm. The work done by the gas can be calculated using the equation W = -∫p dV, where pV^γ remains constant during the process. It is valid to use initial conditions to find the final volume (V_f) since p_i V_i^γ = p_f V_f^γ holds true for adiabatic processes. The discussion emphasizes that both initial and final conditions can be utilized in calculations, and alternative methods such as using changes in internal energy can also be applied. Understanding these principles is crucial for solving the problem effectively.
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Homework Statement


An ideal diatomic gas undergoes an adiabatic compression. Its initial pressure and volume are 1.20 atm and 0.200 m^3 and its final pressure is 2.40 atm. How much work is done by the gas?

Homework Equations


W = -\int p \cdot dV

The Attempt at a Solution


So after integrating I got: W = -pV^{\gamma} \cdot \frac{{V_f}^{1 - \gamma} - {V_i}^{1 - \gamma}}{1 - \gamma}

My first question: How do I know what pV^{\gamma} is? Do I use the final pressure and volume for this constant term?

Second: How do I find V_f? I don't see any equation I can use to solve for it using only final pressure.
 
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PhizKid said:
My first question: How do I know what pV^{\gamma} is? Do I use the final pressure and volume for this constant term?
You know the initial pressure and the initial volume. Why not use those?

PhizKid said:
Second: How do I find V_f? I don't see any equation I can use to solve for it using only final pressure.
How about ##p V^\gamma = \mathrm{const.}##?
 
DrClaude said:
You know the initial pressure and the initial volume. Why not use those?
I wasn't sure if that was a valid substitution. How do you know you are allowed to use the initial conditions and not something else? Can I use either initial or final conditions (provided I know the final conditions) for that substitution?

DrClaude said:
How about ##p V^\gamma = \mathrm{const.}##?
Oh...is ##p_{i} V_{i}^{\gamma} = p_{f} V_{f}^{\gamma}##? Or are you implying something else? If ##p_{i} V_{i}^{\gamma} = p_{f} V_{f}^{\gamma}## is true, how do you know it's true? I don't see why we can assume the initial adiabatic pressure and volume conditions must equal the final ones.
 
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PhizKid said:
I wasn't sure if that was a valid substitution. How do you know you are allowed to use the initial conditions and not something else? Can I use either initial or final conditions (provided I know the final conditions) for that substitution?


Oh...is ##p_{i} V_{i}^{\gamma} = p_{f} V_{f}^{\gamma}##? Or are you implying something else? If ##p_{i} V_{i}^{\gamma} = p_{f} V_{f}^{\gamma}## is true, how do you know it's true? I don't see why we can assume the initial adiabatic pressure and volume conditions must equal the final ones.
Both points I was making rest on the same idea: during an adiabatic process, ##V^\gamma p = \mathrm{const.}## ##\gamma## is not called the adiabatic exponent for nothing! You should find the proof for this in any thermodynamics textbook. The conclusion is that you can use the initial conditions as well as the final conditions in the equation for work, and the initial conditions you already have. Also, you can use ##p_{i} V_{i}^{\gamma} = p_{f} V_{f}^{\gamma}## to find ##V_f##.
 
Thank you very much DrClaude
 
PhizKid said:
... How much work is done by the gas?


Homework Equations


W = -\int p \cdot dV
For work done BY the gas, W = ∫PdV. For work done ON the gas W = -∫PdV

You can also solve this problem by using W = -ΔU = nCVΔT (since Q = 0). You cannot determine ΔT or n but you can determine nΔT quite easily.

AM
 
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