Criteria for choosing a substrate for thin films

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Discussion Overview

The discussion focuses on the criteria for selecting substrates for depositing thin films, addressing both physical and chemical properties necessary for compatibility. It includes considerations for various deposition methods and specific material choices.

Discussion Character

  • Technical explanation
  • Debate/contested
  • Experimental/applied

Main Points Raised

  • Some participants propose that for epitaxial growth, the crystal structure and lattice constants of the substrate should closely match those of the deposited film.
  • It is suggested that the surface properties, such as hydrophobicity or hydrophilicity, should align with the solvent's polarity when depositing liquids on solids.
  • One participant notes that physical deposition techniques like e-beam evaporation allow for a wide range of materials to be deposited on various substrates, emphasizing the importance of clean, flat surfaces.
  • A participant expresses interest in depositing ZnO thin films on a silicon substrate using spray pyrolysis, questioning the preference for silicon over other substrates in existing literature.
  • Another participant speculates that the availability of silicon may be a factor in its frequent use for non-epitaxial growth.

Areas of Agreement / Disagreement

Participants present multiple viewpoints regarding the criteria for substrate selection, with no consensus reached on the most important factors or the reasons for the preference of silicon as a substrate.

Contextual Notes

Limitations include the lack of detailed exploration of specific physical and chemical properties required for different deposition methods, as well as the absence of empirical data to support claims regarding substrate preferences.

ralden
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Hi guys!, i want to know what are the criteria in choosing a substrate to deposit thin films, like what are the physical and chemical properties of the substrate to be compatible in depositing thin films?
 
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ralden said:
Hi guys!, i want to know what are the criteria in choosing a substrate to deposit thin films, like what are the physical and chemical properties of the substrate to be compatible in depositing thin films?

If you are aiming for epitaxy, then the crystal structure and lattice constants of the substrate should be similar to the film you are depositing.
if you want a liquid on a solid then the surface should be hydrophobic or hydrophilic depending on if the solvent is nonpolar or polar.

Using physical deposition, such as e-beam evaporation, you can deposit just about anything on anything else.
Generally you want very clean, flat surfaces.
Also look up sputtering, CVD, PECVD, MOCVD, PVD, etc.
 
Hyo X said:
If you are aiming for epitaxy, then the crystal structure and lattice constants of the substrate should be similar to the film you are depositing.
if you want a liquid on a solid then the surface should be hydrophobic or hydrophilic depending on if the solvent is nonpolar or polar.

Using physical deposition, such as e-beam evaporation, you can deposit just about anything on anything else.
Generally you want very clean, flat surfaces.
Also look up sputtering, CVD, PECVD, MOCVD, PVD, etc.

I want to deposit ZnO (n-type) thin films in Silicon (p-type) substrate using spray pyrolysis, but i don't know the reasons why many articles choose silicon over other substrates
 
if not for epitaxial growth, then i would guess availability.
 

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