Deriving continuity equation of phase space in Statistical Mechanics

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SUMMARY

The discussion focuses on deriving the continuity equation in phase space within Statistical Mechanics, emphasizing that phase space points are conserved. The Leibniz rule for integration in three dimensions is applied to express the relationship between the change in phase points and their density function, denoted as ##\rho(p,q,t)##. The key conclusion is that while phase points can flow across the boundary of a volume, their total number within the volume remains constant, leading to the equation ##\frac{d}{dt} N_{D}(t) = 0##. The participant seeks clarification on the implications of this conservation principle regarding changes in density over time.

PREREQUISITES
  • Understanding of Statistical Mechanics concepts, particularly phase space.
  • Familiarity with the Leibniz rule for integration in multiple dimensions.
  • Knowledge of density functions in the context of phase space, specifically ##\rho(p,q,t)##.
  • Basic grasp of vector calculus, including surface integrals and normal vectors.
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  • Study the derivation of the continuity equation in Statistical Mechanics.
  • Explore the implications of the conservation of phase points in different physical systems.
  • Learn about the role of density functions in fluid dynamics and their relation to phase space.
  • Investigate advanced topics in vector calculus, focusing on surface integrals and their applications.
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binbagsss
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Hi,

So I am aiming to derive the continuity equation using the fact that phase space points are not created/destroyed.

So I am going to use the Leibiniz rule for integration extended to 3-d:

## d/dt \int\limits_{v(t)} F dv = \int\limits_{v(t)} \frac{\partial F}{\partial t} dV + \int\limits_{A(t)} F \vec{u_{A}}.\vec{n} dA ##,

##\vec{n}## the normal unit vector, where ##F=F(x_{1},x_{2},x_{3},t) ##

##\vec{u_{A}} ## is the surface velocity.

So let ##N_{D}## denote the number of phase points in a volume element ##D##, ##N## the total number of phase points.

Conservation of phase points =>
## \frac{d}{dt} N_{D}(t) =0 ##

## = - N \frac{d}{dt} \int\limits_{D} dp dq \rho (p,q,t) ##

where ##\rho = \rho (p,q,t) ## is the density of function.

So by Leibniz rule above I get a term describing the change due to the changing surface of ##A## - ## \partial D ## here

## = - N \int\limits_{\partial D} \rho \vec{V}.\vec{n} d\sigma ##, which is fine ,

where ##\vec{V}## is the velocityMY QUESTION:

The corresponding term to ##\int\limits_{v(t)} \frac{\partial F}{\partial t} dV ## is zero here.
I.e the contribution due to the change of ##\rho## within ##V##. I'm just having a little trouble understanding this conceptually... so my book states that:

"Since phase points cannot be created the only way that phase points can be added or subtracted from the volume V is to flow across its boundary, S. "

That's fine, and seems to make sense to me. But, if points are flowing across the boundary then surely the number inside V is changing. So looking at
## \int\limits_{v(t)} \frac{\partial \rho}{\partial t} dV ##,

##\frac{\partial \rho}{\partial t} \neq 0 ## if there is either a change in the number of phase points or a change in the volume, doesn't saying that the number is changing across the surface => number is changing within the volume and so ##\neq 0 ## for a given volume due to the number of phase points changing?

( I am fine with the rest of the derivation just stuck in this step)

Many thanks in advance.
 
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