Find Heat Energy Needed to Expand Gas to Triple Volume

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SUMMARY

The discussion focuses on calculating the heat energy required to expand 0.40 mol of oxygen (O2) gas to triple its volume at constant pressure. The correct approach involves using the equation Q = ΔH = m C_P ΔT, where the heat capacity (C_P) for oxygen is 0.919 kJ/kg K. The final calculation yields a heat energy requirement of 6.426 kJ, correcting an initial miscalculation that resulted in 3211 kJ due to a unit conversion error in molar mass.

PREREQUISITES
  • Understanding of the ideal gas law (pV=nRT)
  • Knowledge of isobaric processes and heat capacity (C_P)
  • Familiarity with unit conversions, particularly between grams and kilograms
  • Basic thermodynamics principles related to heat transfer
NEXT STEPS
  • Study the ideal gas law and its applications in thermodynamics
  • Learn about isobaric processes and their significance in heat calculations
  • Review unit conversion techniques, especially for molar mass
  • Explore the concept of enthalpy and its relation to heat transfer in gases
USEFUL FOR

This discussion is beneficial for students in chemistry or physics, particularly those studying thermodynamics, as well as educators and anyone involved in gas law applications and heat transfer calculations.

Munir M
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Homework Statement


When 0.40 mol of oxygen(O2) gas is heated at constant pressure starting at 0 degrees C, how much energy must be added to the gas as heat to triple its volume? (The molecules rotate but do not oscillate)

Homework Equations


pV=nRT
p1V1/T1=p2V2/T2
Q=mcdT
Value of Cp for Oxygen I used is 0.919 kJ/kg K

The Attempt at a Solution


I used the equation pV=nRT to get the value of pV at 273K which was pV=907.5. I tripled that value to get 2722.5. Then, using p1V1/T1=p2V2/T2, I plugged in the values to get the final temperature(819K). From that I used Q=mcdT which gave me the answer of 3211kJ. The answer in the back was 6.4 kJ.
 
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You must have missed a conversion factor somewhere, your temperatures are correct. For an isobaric process and constant heat capacity:
Q= \Delta H = m C_P \Delta T
Q = 0.4 \ mol \left(0.032 \frac{kg}{mol} \right) \left( 0.919 \frac{kJ}{kg \cdot K} \right) (819.45 \ K - 273.15 \ K) = 6.426 \ kJ
 
MexChemE said:
You must have missed a conversion factor somewhere, your temperatures are correct. For an isobaric process and constant heat capacity:
Q= \Delta H = m C_P \Delta T
Q = 0.4 \ mol \left(0.032 \frac{kg}{mol} \right) \left( 0.919 \frac{kJ}{kg \cdot K} \right) (819.45 \ K - 273.15 \ K) = 6.426 \ kJ

My mistake was using gmol-1 instead of kgmol-1 for the molar mass. Thanks!
 

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