Finding equilibrium temperature when there are phase changes

AI Thread Summary
The discussion focuses on determining the equilibrium temperature when phase changes occur, specifically with ice and water. The initial formula for equilibrium temperature without phase changes is modified to account for the latent heat of fusion when ice freezes. Participants highlight that if the equilibrium temperature is above 0 °C, only water exists; if below, only ice is present, and at exactly 0 °C, a mixture occurs. To solve the problem, one must calculate the heat required to raise the ice to 0 °C and the heat lost by the water as it cools to 0 °C. Understanding these calculations is essential to determine the final state of the system.
lorenz0
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Homework Statement
In a box containing ##m_{ice}=0.42kg## of ice at a temperature ##T_{ice}=-15°C##, ##m_{w}=0.16kg## of water at a temperature ##T_w=12°C## are added.
Ignore all dispersions of heat in the environment.
Find the equilibrium temperature and how much ice and how much water there is in the equilibrium state.
Relevant Equations
##\sum \Delta Q=0##
If there weren't phase changes occurring I know that the temperature equilibrium would be ##T_e=\frac{m_{ice}c_{ice}T_{ice}+m_{w}c_{w}T_{w}}{m_{ice}c_{ice}+m_{w}c_{w}}##.
Now, by repeating the reasoning to get the above formula (##\sum \Delta Q=0##) and adding the phase changes of the water freezing I get ##T_e=\frac{ m_{ice}c_{ice}T_{ice}+m_{w}c_{w}T_{w}-\delta m_w L_c }{m_{ice}c_{ice}+m_{w}c_{w}}##, where ##L_c## is the latent heat of fusion and condensation, respectively, but how do I find how much (##\delta m_w##) of the water freezes?

And, is my reasoning correct in general? I would like to understand this process in general. Thanks
 
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lorenz0 said:
Homework Statement:: In a box containing ##m_{ice}=0.42kg## of ice at a temperature ##T_{ice}=-15°C##, ##m_{w}=0.16kg## of water at a temperature ##T_w=12°C## are added.
Ignore all dispersions of heat in the environment.
Find the equilibrium temperature and how much ice and how much water there is in the equilibrium state.
Relevant Equations:: ##\sum \Delta Q=0##

If there weren't phase changes occurring I know that the temperature equilibrium would be ##T_e=\frac{m_{ice}c_{ice}T_{ice}+m_{w}c_{w}T_{w}}{m_{ice}c_{ice}+m_{w}c_{w}}##.
Now, by repeating the reasoning to get the above formula (##\sum \Delta Q=0##) and adding the phase changes of the water freezing I get ##T_e=\frac{ m_{ice}c_{ice}T_{ice}+m_{w}c_{w}T_{w}-\delta m_w L_c }{m_{ice}c_{ice}+m_{w}c_{w}}##, where ##L_c## is the latent heat of fusion and condensation, respectively, but how do I find how much (##\delta m_w##) of the water freezes?

And, is my reasoning correct in general? I would like to understand this process in general. Thanks
The second part of the question seems strange.
If Te is above 0 °C then you should have only water, below only ice.
Only if Te = 0 °C you can have a mixture.
Well, maybe that is how you have to deal with it.
Otherwise there are too many unknowns.
 
Philip Koeck said:
The second part of the question seems strange.
If Te is above 0 °C then you should have only water, below only ice.
Only if Te = 0 °C you can have a mixture.
Well, maybe that is how you have to deal with it.
Otherwise there are too many unknowns.
It may be that the second part is poorly phrased because whoever wrote it does not want to prejudice the thinking of the reader. There are three possibilities for the contents:
  1. Only ice at some equilibrium temperature
  2. Only water at some equilibrium temperature
  3. A mixture of ice and water at 0 °C
In the first two cases the mass of the single phase is 0.58 kg and one has to find its temperature. In the third case the temperature of the mixture is 0 °C and one has to find how much of it is ice and how much is water.
To @lorenz0 : Remember that
  • The temperature of the ice must be raised to 0 °C before any of it starts melting and the heat for that to happen can only come from the water. Calculate how much heat.
  • The temperature of the water must be lowered to 0 °C before any of it starts freezing and the heat lost for that to happen can only go into the ice. Calculate how much heat.
Once you have the two numbers, you can figure out which of the three possibilities is the case here and proceed from there.
 
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