To determine the conditions for an electron to pass over a potential well, the relationship between the electron's energy and the potential depth is crucial. When the electron's energy (E) is less than the potential barrier (Ub), it can still tunnel through due to its wave nature. The discussion highlights the importance of the Schrödinger equation in analyzing the wave function of the electron, which is expressed as A exp(ikx). The energy of the electron is clarified to be 8 eV when considering its total energy relative to the well, while the energy remains conserved at 3 eV when discussing its state within the well. Understanding these principles is essential for solving the problem effectively.