Phase transition under pressure?

In summary, the conversation discusses the effects of pressure on crystals, specifically whether a crystal always undergoes a phase transition when pressure is applied and if pressure can be increased without increasing temperature. It is mentioned that some crystals may melt under pressure and that there may be technical difficulties in applying high pressure without a temperature rise. The conversation also briefly mentions Perovskites semiconductor crystals and the challenges of breaking symmetry and increasing pressure in them.
  • #1
new_986
39
0
hello everybody
does always phase undergoes transition when a pressure applied on a crystal ?even when the temperature is constant? and can pressure be increased without increasing temperature for a crystal?

best regards
Nawzad
 
Last edited:
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  • #2
Not always. Some crystals (like ordinary water ice, silver or iron) actually melts if pressure is applied.
Also, it is possible to apply large pressure without temperature rise, but it runs in various technical difficulties because you need long time to dissipate the heat inevitably produced in fast, nearly adiabatic compression.
 
  • #3
Dear Trurle
Thanks for the reply
I am working on Perovskites semiconductor crystal theoretically, my software doesn't break symmetry automatically, I can increase to very high pressures with the same phase (e.g. cubic)
Do have any idea about Perovskites please ??
Thanks again

Nawzad
 

1. What is a phase transition?

A phase transition is the physical process in which a substance undergoes a change in its state of matter, such as from solid to liquid or from liquid to gas.

2. What is pressure?

Pressure is defined as the force exerted on a surface per unit area. In the context of phase transition, pressure refers to the external force applied to a substance that can cause it to change its state of matter.

3. How does pressure affect phase transition?

Pressure plays a crucial role in phase transition as it can change the thermodynamic conditions of a substance, altering its state of matter. For example, increasing pressure can cause a solid to melt into a liquid, or a liquid to vaporize into a gas.

4. What is high-pressure phase transition?

High-pressure phase transition refers to the process of changing a substance's state of matter under high levels of pressure. This can result in the formation of new phases or the suppression of existing phases, leading to unique material properties.

5. What are some examples of phase transition under pressure?

Some examples of phase transition under pressure include the melting of ice into water at high pressures, the formation of diamonds from carbon under extreme pressure and temperature, and the transformation of graphite into graphene under high-pressure conditions.

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