Work & Heat Transfer: Newton's 3rd Law & Internal Energy

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The internal energy of a system changes with the transfer of work or heat between it and its environment. When compressing a gas, work is done on the gas, increasing its internal energy, but according to Newton's third law, the gas also exerts work on its surroundings. This interaction is accounted for as the gas performs negative work on the surroundings due to the opposing direction of force and displacement. The forces between the system and its surroundings are equal and opposite, leading to different signs for the work done. Understanding these dynamics clarifies how energy transfer operates in thermodynamic systems.
HummusAkemi
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So the internal energy of a system changes if work or heat is transferred between itself and its environment. Say you compress a gas and therefore do work on it, increasing its internal energy. According to Newton's 3rd law, shouldn't the gas also do work on its surroundings. How come this isn't accounted for?
 
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HummusAkemi said:
So the internal energy of a system changes if work or heat is transferred between itself and its environment. Say you compress a gas and therefore do work on it, increasing its internal energy. According to Newton's 3rd law, shouldn't the gas also do work on its surroundings. How come this isn't accounted for?
Who says it's not accounted for? Given a specific setup, you could for example, have one piston compressing gas and another piston using that compression but with a different ratio. If on the other hand, you have a fixed container, nothing is moving so no work is being done on the container.
 
HummusAkemi said:
So the internal energy of a system changes if work or heat is transferred between itself and its environment. Say you compress a gas and therefore do work on it, increasing its internal energy. According to Newton's 3rd law, shouldn't the gas also do work on its surroundings. How come this isn't accounted for?
It is accounted for. The gas is doing negative work on the surroundings.

Chet
 
The forces (of the surroundings on the system and of the system on the surroundings) are equal and opposite. But the displacement over which those forces operates is the same for both forces. The force exerted by the surroundings on the system is in the direction of the displacement, so the work done by the surroundings on the system is positive. But the force exerted by the system on the surroundings is in the opposite direction of displacement so the work done by the system on the surroundings is negative.

AM
 
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