Calcium Concentration in Milk: EDTA Titration Problem and Buffering Explained"

In summary, a sample of powdered milk weighing 1.450 g was mixed with a buffer of pH 11.5 and Calagmite indicator. It required 31.62 mL of 1.539x10^-2 M EDTA to reach the end-point color change. The concentration of calcium in the milk can be calculated using the equation M1V1 = M2V2. The solution needs to be buffered to maintain a constant pH and prevent any interference with the color change of the indicator.
  • #1
kkln1212
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Homework Statement



A sample of powdered milk weighing 1.450 g was mixed with an aqueous buffer of pH 11.5. A few drops of Calagmite indicator were added and the solution required 31.62 mL of 1.539x10^-2 M EDTA to reach the end-point color change.

a. Calculate the concentration of calcium in the milk.
b. Why does the solution need to be buffered?

Homework Equations



M1V1 = M2V2

The Attempt at a Solution


I really don't know how to solve this problem
 
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  • #3
EDTA complexes 1:1 with calcium. Calagmite turns red when it is added to the milk by complexing with free calcium until enough EDTA is added to grab it away. When enough EDTA has been added, the calcium-free indicator fades to colorless.
 
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