Can vapor condensation cause significant drop in vapor flow rate?

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SUMMARY

The discussion centers on the significant drop in vapor flow rate observed in a water scrubber system installed for controlling methanol emissions. The outlet flow rate is approximately 30% of the inlet flow rate, with lab analysis indicating a methanol concentration of 20% in the scrubbing liquid. A 95% reduction in ppm from inlet to outlet suggests effective methanol removal. The primary inquiry is how to demonstrate that the flow loss is attributable to methanol condensation and absorption in the water scrubber.

PREREQUISITES
  • Understanding of vapor-liquid equilibrium principles
  • Familiarity with water scrubber systems and their operation
  • Knowledge of mass flow balance calculations
  • Basic concepts of gas absorption and condensation phenomena
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  • Research methods for calculating vapor-liquid mass transfer in scrubbers
  • Explore literature on methanol condensation and absorption in water
  • Learn about the design and efficiency metrics of water scrubber systems
  • Investigate techniques for measuring gas flow rates and concentrations in emissions control
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Environmental engineers, process engineers, and anyone involved in emissions control and vapor management in industrial settings.

MeoH Scrubber
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Need some help here! My plant just installed a water scrubber for controlling methanol emissions. Results obtained from stack tests have consistently shown the flow rate of the gasses from the scrubber outlet is about 30% of gas flow rate into the scrubber. From process knowledge, most of the vapor is methanol.

Further, Lab analysis on the scrubbing liquid shows as much as 20% methanol concentration (200,000 PPM) before it is changed out with fresh water. Stack tests also show an average 95% reduction in ppm measured from the inlet and outlet vents. Clearly, there is some MeOH removal going on.

My problem is this: How do I go about proving that the flow loss is due to condensation and absorption of methanol in the water?

I will like to start with some qualitative argument and then, support it with some calculations if required. Is there some literature out there that can help?
 
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Isn't that what the scrubber system is for, to remove the methanol before it goes up the stack? Or do you think someone is stealing methanol?
 
SteamKing, Thanks.

Mass flow into the scrubber should equal mass flow out. Flow rate of the gasses from the scrubber outlet is about 30% of gas flow rate into the scrubber. I am looking for a method hopefully to prove that the loss of flow (about 70%) is due to methanol condensation.

Thanks again.
 

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