To calculate the volume occupied by 2.0 g of helium at 25°C and 775 mmHg, first convert the mass of helium to moles using its molar mass. The ideal gas law equation, PV = nRT, is used, where R is the universal gas constant (8.314472 J/mol·K). Ensure that pressure is converted from mmHg to pascals for correct unit consistency. After substituting the values into the equation and solving, the volume can be determined. The discussion emphasizes the importance of unit conversion and proper application of the gas law.