It should be simple: it's only trig, right?

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I'm trying to determine the angle between an edge of a unit cube and either space diagonal which shares an end point with said edge (to the end that I may represent a vertex of the unit cube in spherical coordinates.)

My work: A face diagonal of the unit cube is of length \sqrt{1^2+1^2}=\sqrt{2} by the Pythagorean theorem, now the right triangle having an edge and a face diagonal for its legs and a space diagonal as its hypotenuse gives the space diagonal's length as being \sqrt{1^2+( \sqrt{2} )^2}=\sqrt{3} again by the Pythagorean theorem. Hence the desired angle is given by \mbox{arcsin} \left( \sqrt{\frac{2}{3}}\right) or, equivalently, by \mbox{arccos} \left( \frac{1}{\sqrt{3}}\right), yet I cannot determine an exact value for this angle (which I expect to be able to find given the simple geometric nature of the problem,) a numeric approximation of this angle is 54.7357... degrees.

Did I make a mistake? Is there some trick to this?
 
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I doubt that there is a simple expression for that angle, aside from simply writing it as something like \cos^{-1} (1/\sqrt{3}).


p.s. what is the reason to express it in spherical coordinates? Maybe there is a better approach that avoids the need for real numbers!
 
I am trying to prove that a particular sequence of sets converges to the unit hypercube (see https://www.physicsforums.com/showthread.php?t=104727), in particular I was working the 3-d case, finding the points on the surface x^{2N}+y^{2N}+z^{2N}=1 which are furthest from (closest to) the origin using spherical coordinates. I have since found a much simpler method for determining said extrema in the n-D case using the method of Lagrange multipliers but the angle thing was still bugging me.
 
Prove $$\int\limits_0^{\sqrt2/4}\frac{1}{\sqrt{x-x^2}}\arcsin\sqrt{\frac{(x-1)\left(x-1+x\sqrt{9-16x}\right)}{1-2x}} \, \mathrm dx = \frac{\pi^2}{8}.$$ Let $$I = \int\limits_0^{\sqrt 2 / 4}\frac{1}{\sqrt{x-x^2}}\arcsin\sqrt{\frac{(x-1)\left(x-1+x\sqrt{9-16x}\right)}{1-2x}} \, \mathrm dx. \tag{1}$$ The representation integral of ##\arcsin## is $$\arcsin u = \int\limits_{0}^{1} \frac{\mathrm dt}{\sqrt{1-t^2}}, \qquad 0 \leqslant u \leqslant 1.$$ Plugging identity above into ##(1)## with ##u...

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