A chemical reaction is a process that leads to the chemical transformation of one set of chemical substances to another. Classically, chemical reactions encompass changes that only involve the positions of electrons in the forming and breaking of chemical bonds between atoms, with no change to the nuclei (no change to the elements present), and can often be described by a chemical equation. Nuclear chemistry is a sub-discipline of chemistry that involves the chemical reactions of unstable and radioactive elements where both electronic and nuclear changes can occur.
The substance (or substances) initially involved in a chemical reaction are called reactants or reagents. Chemical reactions are usually characterized by a chemical change, and they yield one or more products, which usually have properties different from the reactants. Reactions often consist of a sequence of individual sub-steps, the so-called elementary reactions, and the information on the precise course of action is part of the reaction mechanism. Chemical reactions are described with chemical equations, which symbolically present the starting materials, end products, and sometimes intermediate products and reaction conditions.
Chemical reactions happen at a characteristic reaction rate at a given temperature and chemical concentration. Typically, reaction rates increase with increasing temperature because there is more thermal energy available to reach the activation energy necessary for breaking bonds between atoms.
Reactions may proceed in the forward or reverse direction until they go to completion or reach equilibrium. Reactions that proceed in the forward direction to approach equilibrium are often described as spontaneous, requiring no input of free energy to go forward. Non-spontaneous reactions require input of free energy to go forward (examples include charging a battery by applying an external electrical power source, or photosynthesis driven by absorption of electromagnetic radiation in the form of sunlight).
A reaction may be classified as redox in which oxidation and reduction occur or nonredox in which there is no oxidation and reduction occurring. Most simple redox reactions may be classified as combination, decomposition, or single displacement reactions.
Different chemical reactions are used during chemical synthesis in order to obtain a desired product. In biochemistry, a consecutive series of chemical reactions (where the product of one reaction is the reactant of the next reaction) form metabolic pathways. These reactions are often catalyzed by protein enzymes. Enzymes increase the rates of biochemical reactions, so that metabolic syntheses and decompositions impossible under ordinary conditions can occur at the temperatures and concentrations present within a cell.
The general concept of a chemical reaction has been extended to reactions between entities smaller than atoms, including nuclear reactions, radioactive decays, and reactions between elementary particles, as described by quantum field theory.
I remember when I was in high school, heat was very often said to be a factor of speeding up chemical reactions that we all know, because heat is actually energy, energy will excite the molecules and make them easier to collide with other molecules or leave its own molecules (breaking bond)...
Hi,
I have to determine the reaction mechanism of this molecule.
Can someone please explain to me why the reaction would occur on OH (A)?
Is it bc you can't have 2 pi bonds next to each other and OH(A) is the only polarised bond in the molecule where it would easily break off and form a double...
I am trying to understand the reaction of a steel coil compression spring when pulsed. The spring I am interested in has the following physical characteristics:
k (spring constant in pounds per inch) = 2.88
d (wire diameter in inches) = .043
n (number of active coils) = 29
D (mean diameter of...
Hi,
I was attempting the following question and don't know how to find the 'reaction rate':
"For the reaction the following stoichiometric coefficients have been determined: 2 ##C## react to form 2 ##E## and 1 ##F##. The rate of formation of E is ##1.6\times10^{–4} mol L^{–1} s^{–1}##. What is...
Hey,
I have this equation in which I have to determine its reaction mechanism.
I managed to determine how we managed to obtain this the molecule in the picture above, but I don't understand the mechanism behind obtaining the second alkene. Thank you so much for your help, and sorry if the...
(This added about a month after this thread opened: It turns out I'm a real outlier for side effects to the vaccine, so don't let this post scare you off. My wife says every time I catch a cold or something that it hits me hard. Of course to me that is 'normal.' :doh:)
A few days ago a...
I think I should use ln(K2/K1)=Ea/R(1/T1 - 1/T2), and find K2/K1. I am given T1 and T2, but not Ea. I'm not sure how to continue.
Thanks.
(note: the answer is C)
I accelerate charged particle ##A## causing virtual photons to travel to distant charged particle ##B## which feels an electromagnetic force proportional to ##A##'s acceleration (for a classical field description of this effect see https://www.feynmanlectures.caltech.edu/I_28.html Eqn 28.6)...
I'm so sorry if this is a bad question!
I am doing an experiment measuring the rate of gas production (hydrogen) of the electrolysis of water, and I got myself a bit confused about whether I have been taking the correct measurements?
I had originally thought that, since the "concentration" of...
I know how to get fusion cross section plots from the exfor website but now I need to plot the reaction rate as a function of temperature. According to the image, I have sigma and E values as x and y data. How do I integrate using MATLAB .
I am stuck, i have compute the total moles as :
## n_{tot}=\frac{P_{tot*V}}{RT}##=0,125 mol
##Kp= \frac{P_{tot}\frac {n_{PCL_3}}{n_{tot}}*P_{tot}\frac {n_{CL_2}}{n_{tot}}}{P_{tot} \frac {n_{PCL_3}}{n_{tot}}}=\frac {P_{tot}}{n_{tot}}*\frac {n_{PCL_3}n_{CL_2}}{n_{PCL_5}}##
From here, can't go...
Hi,
I understood that to calculate the available energy in these two reactions could be calculated from Ed = [Mn(X) – (Mn(Y) + m(e))] c^2, but when I have to change use the atoms' mass instead of the nucleons' mass, it gives out two different formulas :
Ed = [M(X) – M (Y)] c2 for β-
Ed = [M(X)...
Given: r1 = 0.75 r2 = 1.5
Ok, i have done statics and dynamics, but this book does things differently than the way i accomplished it in the previous classes. This is for mechanical engineering design class.
Here is my question. They take sum of the moments along X, which goes through the center...
Summary:: A tertiary allylic alcohol rearranges to become a primary allylic alcohol, would it be exothermic because the final product is more stable and lower in energy?
Hi all, this problem's been on my mind for a couple of days now and I'm not making any progress with it. My problem is that...
Trying to determine the reaction torque a person would have to supply to keep the auger head from spinning when the ice auger is drilling a hole
So I am an ice fisherman and I got thinking, when you drill a hole with an ice auger, the head always wants to turn opposite of the auger bit. You have...
a.)N cos θ=mg
N sin θ=mrw^2 sin θ
cos θ=g/rw^2
b.) My question is reaction force =N ? or =F=mg tanθ ?
If it is N then N=mg cosθ =mg^2/r w^2 or N=mg/cosθ =mrw^2 ?
Thank you
Summary:: Theoretical reaction force due to ball traveling in a semi-circle circum
Hi,
Can anyone please help me with the following question:
Setup...
1 x length of pipe bent 180 degrees with an inner diameter of 22mm, it's radius is 2mtrs, the mass of this object is 100kg. Total length of...
For the reaction between hydrogen peroxide and sodium hypochlorite, is the OCl- both reduced and oxidized?
H2O2 + NaOCl -> NaCl + H2O + O2
Oxidation states:
+1 -1 +1 -2 +1 +1 -1 +1 -2 0
From the oxidation...
The principal equilibrium in a solution of NaHCO3 is
HCO3-(aq) + HCO3-(aq) <-> H2CO3(aq) + CO32-(aq)
Calculate the value of the equilibrium constant for this reaction.
My solution:
This overall reaction is the same as the sum of the following reactions:
HCO3-(aq) <-> H2CO3(aq) + OH-(aq)...
Hi
I need to find the amount of fuel needed for a nuclear reaction to produce 800MW daily . The reaction is
n + 𝟗𝟒𝑷𝒖 𝟐𝟑𝟗 → 𝟓𝟐𝑻𝒆 𝟏𝟑𝟒 + 𝟒𝟐𝑴𝒐 𝟏𝟎𝟑 + 𝟑 𝒏
Can you please give me a hint on how to do this?
Thank you very much for your help
Hello everyone,
For this equation, I have found Ay as 0.677kN by using Ma = 1.5kN(7m)-Ay(15.5m).
To find Cy, would I be using the sum of forces to find the answer?
For example Fy = Ay - F2 - F1sin55 + Cy = 0
This would then get Cy answer as 2.05kN
Hi
I'm having trouble to understand the centripetal force in a rotating rod with a mass in its end.
When ##90°<\theta<270°##, the centripetal acceleration is produced by the tension, which counteracts the radial component of the weight.
But what happens when ##\theta<90°## or ##\theta>270°##...
The following is a basic surface-catalyzed isomerization reaction:
A -> P
This can be modeled by the following mechanism:
A + S -> A-S
A-S -> P + S
The text is trying to derive the rate law for the formation of P.
d[P]/dt = k[A-S]
It can also be written as
d[P]/dt = k'[thetaA], where thetaA is...
I know that
##\vec{v_c}=(\omega_1;-\omega_2;0)×(L;-r;0)=0##
So ##\omega_2=\frac{r\omega_1}{L}##
Then, using the system of coordinates shown in the picture and ##\Sigma M_z## I can find the reaction force in ##C##.
But how can I find the reaction forces on ##A## and ##O##? I mean, what system...
With the peroxide solution in excess, we added 10ml vinegar and 10ml of different concentrations of permanganate and timed the reaction. The basics are that the more concentrated the permanganate , the faster the reaction. I would just like to know what the theoretical relationship is between...
The equation can be seen in the picture. I was assuming it was an Sn2 reaction given the polar aprotic solvent and strong nucleophile.
For b), I assumed that the question asked me to draw the orbitals as shown above (as opposed to orbital diagram) because it asked me to identify the HOMO and...
According to a trusted source (a textbook, if you must know), the actual Gibbs free energy of an otherwise reversible reaction, becomes lower than expected if the local circumstances makes the reaction effectively irreversible. The circumstances are that neither enough energy, nor a reaction...
I tried momentum conservation, which gives:
-pα = pdaughter
<=> 2mKα = 2mKdaugther (squaring two sides)
Using the given mass ratio, I found Kdaughter to be 0.0864MeV
Adding the two Kinetic energy of the product particles and converting it to Joules, I got A
But I don't understand why adding the...
Conversion: 1.0 t = 1.0x10^6 g impure Si
Conversion: 2.33 t = 2.33x10^6 g SiCl4
Atomic Mass Si = 28.085 g/mol
Atomic Mass Cl2 = (2 x 35.453) = 70.906 g/mol
Mass SiCl4 = 28.085 + (4x35.453) = 169.897 g/molI got all this part down, however, I'm not quite sure where I am supposed to go from there...
Hi
For a personal project, has the energy level diagram of the below reaction been derived? Voltage Applied4B+2LiNO3+C ------------->B4C+2LiNO2+O2
Thanks,
I'm struggling doing point 5, i have no idea how to solve that question. In point 1 i obtained the following result:
## I=\frac{ML^2}{2}## calculating the integral of dI, the infinitesimal moment of inertia of a small section of the rod of length dr.
2) Through the conservation of angular...
Conversion: 9.65 kg = 9650 g
Mass Al = 26.98 g/mol
Molar Mass Al2O3 = (2 x 26.98) + ( 3 x 16.00) = 101.96 g/mol
Mol Al2O3 = 9650 g / 101.96 g/mol = 94.65 mol
Mol Al Required = 94.65 mol x 2 = 189.3 mol
Mass 100% Al required = 189.3 mol x 26.98 g/mol = 5.107x103 g
Mass 80% Al required =...
hi,
I was asked to balance this reaction :
H3PO4(aq) + KMnO4(aq) + H2SO4(aq) → H3PO4(aq) + MnSO4(aq) + K2SO4(aq) + H2O(l)
can I get some help? why we can't balance this reaction? and what can we say about a reaction that has the same compound as a reagent and a product?
thank you
Summary:: We are given a description of a reaction and the masses of two reactants and are initially asked to calculate which of two is the excess reagent and how much of the excess reagent would be left over if we have 100% completion. Then we are given a final mass (after purification) of the...
Hello PF,
I am building a traction assembly for a self balancing bot project and I am having some conflict with my intuition and practical testing results. The setup consists of a motor mounted to a chassis, the shaft coupled to a wheel that rests on a surface with non-zero friction. Below...
Summary:: In the question below, I've been asked to determine what happens to the reaction when the temperature is increased. I know the answer is a, but I'm having difficulty determining why.
https://www.physicsforums.com/attachments/264126
A car and its load weighs 30kN and the center of gravity is 0.6 m from the ground and midway between the front and rear wheels which are 3m apart. The car is brought to rest from a speed of 50 kph in 5 sec by means of the brakes. Compute the reaction in the front wheel.
Wikipedia says this about the missing mass of a reaction:
I wondered where such an expression is coming from? The invariant mass of a system ##M##, in natural units, satisfies $$M^2 = \left(\sum E \right)^2 - ||\sum \mathbf{p}||^2$$ If anything, then the "missing" mass (which they also...
I'm trying to simulate a simple series reaction stochastically using Gillespie's algorithm. I found this file:
What is this 'propensity function'? Say for example I have the simple reactions:
A --(k1)--> R
R--(k2)--> S
are these 'propensity functions' the rates (a wild guess)? I mean;
α1 =...
Hello,
I mixed these today:
H3PO4
NaOH
Tetrahydrofuran CH₂)₄O
Cyklohexanon C6H10O
2-Butanon C4H8O
It started to generate smoke. Just wondering if this gas might have been dangerous to breath in? theories? experiences?
Thanks
Stan