Effect of temperature on the heat of combustion

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Discussion Overview

The discussion revolves around the effect of temperature on the heat of combustion, exploring definitions and conditions under which heat of combustion is measured. Participants are examining the relationship between heat of combustion and enthalpy, as well as the implications of varying temperature and pressure on combustion reactions.

Discussion Character

  • Exploratory, Technical explanation, Debate/contested

Main Points Raised

  • One participant questions whether heat of combustion is the same as enthalpy.
  • Another participant states that heat of combustion is defined at standard conditions, suggesting that temperature does not affect it.
  • A different participant emphasizes that heats of reactions, including combustion, at non-standard conditions depend on temperature and pressure.
  • Another contribution clarifies that heat of combustion is the difference in enthalpy between products and reactants at specified temperature and pressure, noting the importance of stoichiometric proportions.

Areas of Agreement / Disagreement

There appears to be disagreement among participants regarding the effect of temperature on heat of combustion, with some asserting it is constant at standard conditions while others argue it varies with temperature and pressure.

Contextual Notes

Participants reference standard conditions and the definitions of heat of combustion and enthalpy, but there are unresolved assumptions regarding the implications of temperature and pressure changes on combustion reactions.

kester
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DEvens said:
Standard (my addt'n & emphasis) Heat of combustion is defined at standard conditions.
Heats of reactions/combustions at other conditions are functions of T,P.
 
kester said:
Like in a topic. I just got this question and I am looking for some help.

I found this one http://wikieducator.org/The1stLawofThermodynamicsLesson5 I don't know, is the heat of combustion is the same as entalphy?
Heat of combustion is the difference in enthalpy between the products of the reaction and the reactants at a specified temperature and pressure. It refers to reactants in molar stoichiometric proportions producing products in stoichiometric molar proportions.

Chet
 

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